One-pot synthesis of levulinic acid from cellulose in ionic liquids

被引：71
|
作者：
Shen, Yue [1 ]
Sun, Jian-Kui [1 ]
Yi, Yu-Xuan [1 ]
Wang, Bo [1 ]
Xu, Feng [1 ]
Sun, Run-Cang [1 ]
机构：
[1] Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing Key Lab Lignocellulos Chem, Beijing 100083, Peoples R China
来源：
BIORESOURCE TECHNOLOGY | 2015年 / 192卷
基金：
中国国家自然科学基金;
关键词：
Cellulose; Degradation; Levulinic acid; Ionic liquids; CATALYTIC CONVERSION; ENZYMATIC-HYDROLYSIS; SELECTIVE CONVERSION; SOLVENT; EFFICIENT; SYSTEMS;
D O I：
10.1016/j.biortech.2015.05.080
中图分类号：
S2 [农业工程];
学科分类号：
0828 ;
摘要：
A simple and effective route for the production of levulinic acid (LA) from cellulose has been developed in SO3H-functionalized ionic liquids. The effects of ionic liquid structures, reaction conditions and combination of metal chlorides with ILs on the yield of LA were investigated, where the highest yield of 39.4% was obtained for 120 min in the presence of 1-(4-sulfonic acid) butyl-3-methylimidazolium hydrogen sulphate ([BSMim]HSO4) with addition of H2O. The catalytic activities of ionic liquids depended on the anions and decreased in the order: CF3SO3-> HSO4(-) > OAc-, which was in good agreement with their acidity order. The ILs play a dual solvent-acid role for the cellulose conversion into LA and exhibited favorable catalytic activity over four repeated runs. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：812 / 816
页数：5
相关论文
共 50 条
  • [41] Cellulose-silica composite aerogels from "one-pot" synthesis
    Demilecamps, Arnaud
    Reichenauer, Gudrun
    Rigacci, Arnaud
    Budtova, Tatiana
    CELLULOSE, 2014, 21 (04) : 2625 - 2636
  • [42] One-Pot Synthesis of Luminescent Polymer-Nanoparticle Composites from Task-Specific Ionic Liquids
    Campbell, Paul S.
    Lorbeer, Chantal
    Cybinska, Joanna
    Mudring, Anja-Verena
    ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (23) : 2924 - 2931
  • [43] Fe-functionalized paramagnetic sporopollenin from pollen grains: one-pot synthesis using ionic liquids
    C. Chiappe
    M. J. Rodriguez-Douton
    M. C. Mozzati
    D. Prete
    A. Griesi
    L. Guazzelli
    M. Gemmi
    S. Caporali
    N. Calisi
    C. S. Pomelli
    F. Rossella
    Scientific Reports, 10
  • [44] One-pot synthesis of pyrrolidones from levulinic acid and amines/nitroarenes/nitriles over the Ir-PVP catalyst
    Chaudhari, Chandan
    Shiraishi, Masaya
    Nishida, Yoshihide
    Sato, Katsutoshi
    Nagaoka, Katsutoshi
    GREEN CHEMISTRY, 2020, 22 (22) : 7760 - 7764
  • [45] Efficient one-pot production of 5-hydroxymethylfurfural from inulin in ionic liquids
    Qi, Xinhua
    Watanabe, Masaru
    Aida, Taku M.
    Smith, Richard L., Jr.
    GREEN CHEMISTRY, 2010, 12 (10) : 1855 - 1860
  • [46] Intensified levulinic acid/ester production from cassava by one-pot cascade prehydrolysis and delignification
    Zhao, Weijie
    Li, Yingwen
    Song, Changhua
    Liu, Sijie
    Li, Xuehui
    Long, Jinxing
    APPLIED ENERGY, 2017, 204 : 1094 - 1100
  • [47] One-Pot Van Leusen Synthesis of 4,5-Disubstituted Oxazoles in Ionic Liquids
    Wu, Bo
    Wen, Jun
    Zhang, Ji
    Li, Jing
    Xiang, Yong-Zhe
    Yu, Xiao-Qi
    SYNLETT, 2009, (03) : 500 - 504
  • [48] Dicationic Ionic Liquids as Recyclable Catalysts for One-Pot Solvent-Free Synthesis of α-Aminophosphonates
    Fang, Dong
    Yang, Jinming
    Ni, Chunjie
    HETEROATOM CHEMISTRY, 2011, 22 (01) : 5 - 10
  • [49] A More Sustainable and Cheaper One-Pot Route for the Synthesis of Hydrophobic Ionic Liquids for Electrolyte Applications
    Simonetti, Elisabetta
    De Francesco, Massimo
    Bellusci, Mariangela
    Kim, Guk-Tae
    Wu, FangLin
    Passerini, Stefano
    Appetecchi, Giovanni Battista
    CHEMSUSCHEM, 2019, 12 (22) : 4946 - 4952
  • [50] Facile One-Pot Synthesis of 1-Alkyl-3-polyfluoroalkyl Imidazolium Ionic Liquids
    Kim, Dong Sub
    Natalia, Debby
    Nguyen, Dihn Quan
    Suh, Dong Jin
    Kim, Honggon
    Kim, Hoon Sik
    Lee, Hyunjoo
    SYNLETT, 2009, (13) : 2101 - 2104
12345