Synthesis, characterization, and interaction with DNA of Cu(II) and Zn(II) complexes with 2,2-bipyridyl-6,6-dicarboxylic acid

被引：25

作者：

Sun, Ya-Guang ^{[1
]}

Li, Ke-Long ^{[1
]}

Xu, Zhen-He ^{[1
]}

Lv, Tian-Yi ^{[1
]}

Wang, Shu-Ju ^{[1
]}

You, Li-Xin ^{[1
]}

Ding, Fu ^{[1
]}

机构：

[1] Shenyang Univ Chem Technol, Lab Coordinat Chem, Shenyang, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 14期

关键词：

Dinuclear complex; Mononuclear complex; DNA binding; DNA cleavage; BINDING PROPERTIES; CRYSTAL-STRUCTURES; COPPER(II); CLEAVAGE; LIGAND; PHOTOCLEAVAGE; COBALT(III);

D O I：

10.1080/00958972.2013.806655

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two transition metal complexes, [Cu-2(bpdc)(2)H2O]<bold>2</bold>H2O (1) and Zn(bpdc)(H2O)(2) (2) (H(2)bpdc=2,2-bipyridine-6,6-dicarboxylic acid), were synthesized and characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. Complex 1 is dinuclear with two five-coordinate cupric ions and 2 is mononuclear with one six-coordinate zinc. Interactions of 1 and 2 with DNA have been investigated using UV-Vis absorption spectra. The cleavage reaction on DNA has been monitored by agarose gel electrophoresis.

引用

页码：2455 / 2464

页数：10

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