Synthesis, characterization, and interaction with DNA of Cu(II) and Zn(II) complexes with 2,2-bipyridyl-6,6-dicarboxylic acid

被引：25
|
作者：
Sun, Ya-Guang [1 ]
Li, Ke-Long [1 ]
Xu, Zhen-He [1 ]
Lv, Tian-Yi [1 ]
Wang, Shu-Ju [1 ]
You, Li-Xin [1 ]
Ding, Fu [1 ]
机构：
[1] Shenyang Univ Chem Technol, Lab Coordinat Chem, Shenyang, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 14期
关键词：
Dinuclear complex; Mononuclear complex; DNA binding; DNA cleavage; BINDING PROPERTIES; CRYSTAL-STRUCTURES; COPPER(II); CLEAVAGE; LIGAND; PHOTOCLEAVAGE; COBALT(III);
D O I：
10.1080/00958972.2013.806655
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two transition metal complexes, [Cu-2(bpdc)(2)H2O]<bold>2</bold>H2O (1) and Zn(bpdc)(H2O)(2) (2) (H(2)bpdc=2,2-bipyridine-6,6-dicarboxylic acid), were synthesized and characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. Complex 1 is dinuclear with two five-coordinate cupric ions and 2 is mononuclear with one six-coordinate zinc. Interactions of 1 and 2 with DNA have been investigated using UV-Vis absorption spectra. The cleavage reaction on DNA has been monitored by agarose gel electrophoresis.
引用
收藏
页码：2455 / 2464
页数：10
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