Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure

被引：2

作者：

Rebocho, Silvia ^{[1
]}

Nunes, Ana V. M. ^{[1
]}

Najdanovic-Visak, Vesna ^{[2
]}

Barreiros, Susana ^{[1
]}

Paiva, Alexandre ^{[1
]}

机构：

[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Quim, LAQV REQUIMTE, Quinta Torre, P-2829516 Caparica, Portugal

[2] Univ Lancaster, Energy Lancaster, Dept Engn, Lancaster LA1 4YR, England

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2017年 / 62卷 / 01期

关键词：

CARBON-DIOXIDE; BIOCATALYSIS; EQUATION; EQUILIBRIUM; KINETICS; STATE;

D O I：

10.1021/acs.jced.6b00595

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The phase equilibrium of the binary system (CO2 + propionic anhydride) was determined experimentally at temperatures of 308, 313, and 323 K and pressures up to 10 MPa. Measurements were carried out in a high-pressure visual cell with variable volume. The experimental data were modeled using the Peng-Robinson equation of state and the Mathias-Klotz-Prausnitz mixing rule. A good correlation was achieved with this model, with a total average absolute deviation of 0.21%.

引用

页码：210 / 213

页数：4

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