Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure

被引：2
|
作者：
Rebocho, Silvia [1 ]
Nunes, Ana V. M. [1 ]
Najdanovic-Visak, Vesna [2 ]
Barreiros, Susana [1 ]
Paiva, Alexandre [1 ]
机构：
[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Quim, LAQV REQUIMTE, Quinta Torre, P-2829516 Caparica, Portugal
[2] Univ Lancaster, Energy Lancaster, Dept Engn, Lancaster LA1 4YR, England
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2017年 / 62卷 / 01期
关键词：
CARBON-DIOXIDE; BIOCATALYSIS; EQUATION; EQUILIBRIUM; KINETICS; STATE;
D O I：
10.1021/acs.jced.6b00595
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The phase equilibrium of the binary system (CO2 + propionic anhydride) was determined experimentally at temperatures of 308, 313, and 323 K and pressures up to 10 MPa. Measurements were carried out in a high-pressure visual cell with variable volume. The experimental data were modeled using the Peng-Robinson equation of state and the Mathias-Klotz-Prausnitz mixing rule. A good correlation was achieved with this model, with a total average absolute deviation of 0.21%.
引用
收藏
页码：210 / 213
页数：4
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