Dichlorotetrakis(4-methylimidazole)copper(II)

被引：7
|
作者：
Näther, C [1 ]
Wriedt, M [1 ]
Jess, I [1 ]
机构：
[1] Univ Kiel, Inst Anorgan Chem, D-24098 Kiel, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷
关键词：
D O I：
10.1107/S1600536802000314
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the structure of the title compound, [CuCl2(C4H6N2)(4)], the copper(II) cation is surrounded by four 4-methylimidazole ligands within a slightly distorted square plane. The coordination sphere is completed by two contacts to Cl atoms which are elongated due to the Jahn-Teller distortion. The coordination polyhedron around the copper(II) cations can be described as a strongly distorted octahedron. The copper(II) cations are located on centres of inversion, whereas the two crystallographically independent 4-methylimidazole ligands and the chloride anion occupy general positions. There are short N-H...Cl distances to the Cl atoms indicating hydrogen bonding.
引用
收藏
页码：m39 / m40
页数：2
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