Dichlorotetrakis(4-methylimidazole)copper(II)

被引：7

作者：

Näther, C ^{[1
]}

Wriedt, M ^{[1
]}

Jess, I ^{[1
]}

机构：

[1] Univ Kiel, Inst Anorgan Chem, D-24098 Kiel, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷

关键词：

D O I：

10.1107/S1600536802000314

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the structure of the title compound, [CuCl2(C4H6N2)(4)], the copper(II) cation is surrounded by four 4-methylimidazole ligands within a slightly distorted square plane. The coordination sphere is completed by two contacts to Cl atoms which are elongated due to the Jahn-Teller distortion. The coordination polyhedron around the copper(II) cations can be described as a strongly distorted octahedron. The copper(II) cations are located on centres of inversion, whereas the two crystallographically independent 4-methylimidazole ligands and the chloride anion occupy general positions. There are short N-H...Cl distances to the Cl atoms indicating hydrogen bonding.

引用

页码：m39 / m40

页数：2

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