First example of B-C bond cleavage in the BArF (B[C6H3(CF3)2-3,5]4) anion mediated by a transition metal species, trans-[(Ph3P)2Pt(Me)(OEt2)]+

被引：68

作者：

Konze, WV ^{[1
]}

Scott, BL ^{[1
]}

Kubas, GJ ^{[1
]}

机构：

[1] Univ Calif Los Alamos Natl Lab, Chem Sci & Technol Div, Los Alamos, NM 87545 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a902274k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of transition metal-mediated decomposition of the widely used BArF anion (BArF = B[C6H3(CF3)(2)-3,5](4)) has been accomplished by mild heating of the cationic platinum complex trans-[(Ph3P)(2)Pt(Me)(OEt2)](+)(BArF)(-) in low-coordinating solvents to form the diarylated product trans-(Ph3P)(2)Pt(Ar-F)(2) in good yield, thus demonstrating that such non-interacting anions can react with electrophilic transition metal complexes.

引用

页码：1807 / 1808

页数：2

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