First example of B-C bond cleavage in the BArF (B[C6H3(CF3)2-3,5]4) anion mediated by a transition metal species, trans-[(Ph3P)2Pt(Me)(OEt2)]+

被引：68

作者：

Konze, WV ^{[1
]}

Scott, BL ^{[1
]}

Kubas, GJ ^{[1
]}

机构：

[1] Univ Calif Los Alamos Natl Lab, Chem Sci & Technol Div, Los Alamos, NM 87545 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a902274k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of transition metal-mediated decomposition of the widely used BArF anion (BArF = B[C6H3(CF3)(2)-3,5](4)) has been accomplished by mild heating of the cationic platinum complex trans-[(Ph3P)(2)Pt(Me)(OEt2)](+)(BArF)(-) in low-coordinating solvents to form the diarylated product trans-(Ph3P)(2)Pt(Ar-F)(2) in good yield, thus demonstrating that such non-interacting anions can react with electrophilic transition metal complexes.

引用

页码：1807 / 1808

页数：2

共 50 条

[11] OXIDATIVE-ADDITION AND PROTON-TRANSFER REACTIONS OF FLUOROCARBON ACIDS - STRUCTURES OF TRANS-(PH3P)2PT(H2O)(PHC=CHPH)+HC(SO2CF3)2- AND TRANS-(PH3P)2PTH[C-HC(SO2CF3)2]
SIEDLE, AR
GLEASON, WB
NEWMARK, RA
PIGNOLET, LH
ORGANOMETALLICS, 1986, 5 (10) : 1969 - 1975
[12] A GEM-DIOLATO COMPLEX OF PLATINUM - STRUCTURE OF [(P(C6H5)3)2PT(O2C(CF3)2)]
HYNES, RC
WILLIS, CJ
PAYNE, NC
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 : 42 - 45
[13] PREPARATION AND REACTIONS OF TRANS-[(PPH3)2PT(CH2SR)CL] (R = ME, PH OR C6H4ME-P)
MCPHERSON, HD
WARDELL, JL
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 254 (02) : 261 - 266
[14] The synthesis of the coordination polymer {trans-(Ph3P)2pt[(η2-C≡=CPh)CuX]2}n (3a, X=Cl; 3b, X=Br) and it's reaction towards bipy and [AgNO3] is described.: The solid-state structures of A and trans(Ph3P)2Pt[(η2-C≡CPh)CuNO3]2 are reported as well
Lang, H
del Villar, A
Walfort, B
Rheinwald, G
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (09) : 1464 - 1471
[15] Halide abstraction by Na[B{C6H3(CF3)2-3,5}4]:: Synthesis and structural characterization of the rhodium(I) cations [(η6-arene)Rh(PPh3)2]+ (arene = benzene, toluene)
Buttler, Oliver
Al-Fawaz, Amal
Kays, Deborah L.
Day, Joanna K.
Ooi, Li-Ling
Aldridge, Simon
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (14): : 2187 - 2189
[16] Syntheses and reactivity of cationic borane-ruthenium complexes [(η5-C5R5)Ru(PMe3)2(η1-BH3•EMe3)][BArf4] (R = H, Me; E = N, P; BArf4=[B{3,5-C6H3(CF3)2}4])
Kawano, Yasuro
Hashiva, Masahiro
Shimoi, Mamoru
ORGANOMETALLICS, 2006, 25 (18) : 4420 - 4426
[17] Two isomers of a tris(dimethylamino)bis (trimethylstannyl) triborane(5) and the reaction of (Me3Sn)2B2(NMe2)2 with (Ph3P)2Pt(η2-C2H4)
Habereder, T
Nöth, H
Wagner, M
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2001, (07) : 1665 - 1669
[18] B-FRAME SUPPORTED HETEROBIMETALLIC SPECIES - MOLECULAR-STRUCTURE OF "[(ME3P)2PT(PH3P)(PH2PC6H4)HLRB9H10]
BOULD, J
CROOK, JE
GREENWOOD, NN
KENNEDY, JD
MCDONALD, WS
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (17) : 949 - 950
[19] SYNTHESIS AND SPECTROSCOPIC AND X-RAY STRUCTURAL STUDIES OF THE MESITYLPHOSPHINES PH22,4,6-ME3C6H2 AND PH2,4,6-ME3C6H2 AND THEIR LITHIUM-SALTS [LI(THF)3PH2,4,6-ME3C6H2] AND [(LI(OET2)P2,4,6-ME3C6H22)2]
BARTLETT, RA
OLMSTEAD, MM
POWER, PP
SIGEL, GA
INORGANIC CHEMISTRY, 1987, 26 (12) : 1941 - 1946
[20] STRUCTURE AND REACTIVITY OF THE ANIONIC ALKENEOSMIUM CLUSTER, [1,1,1,2,2,2,3,3,3,3-DECACARBONYL-2-BROMO-1-ETA-2-TRANS-1,1,1,4,4,4-HEXAFLUOROBUT-2-ENE-TRIANGULO-TRIOSMIUM]- - X-RAY CRYSTAL-STRUCTURES OF [(PH3P)2N][OS3(CO)10(CF3(H)C=C(H)CF3)BR], [(PH3P)2N][OS3(CO)9(CF3(H)C=C(H)CF3)(MU-BR)], AND "[HOS3(CO)9(CF3(H)C=C(H)CF3)(MU-BR)]-T
DAWOODI, Z
MAYS, MJ
RAITHBY, PR
HENRICK, K
CLEGG, W
WEBER, G
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 249 (01) : 149 - 164

← 1 2 3 4 5 →