First example of B-C bond cleavage in the BArF (B[C6H3(CF3)2-3,5]4) anion mediated by a transition metal species, trans-[(Ph3P)2Pt(Me)(OEt2)]+

被引：68
|
作者：
Konze, WV [1 ]
Scott, BL [1 ]
Kubas, GJ [1 ]
机构：
[1] Univ Calif Los Alamos Natl Lab, Chem Sci & Technol Div, Los Alamos, NM 87545 USA
来源：
CHEMICAL COMMUNICATIONS | 1999年 / 18期
关键词：
D O I：
10.1039/a902274k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first example of transition metal-mediated decomposition of the widely used BArF anion (BArF = B[C6H3(CF3)(2)-3,5](4)) has been accomplished by mild heating of the cationic platinum complex trans-[(Ph3P)(2)Pt(Me)(OEt2)](+)(BArF)(-) in low-coordinating solvents to form the diarylated product trans-(Ph3P)(2)Pt(Ar-F)(2) in good yield, thus demonstrating that such non-interacting anions can react with electrophilic transition metal complexes.
引用
收藏
页码：1807 / 1808
页数：2
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