Molecular structure of ThBr4(DME)2 (DME=1,2-dimethoxyethane)

被引：8
|
作者：
Rabinovich, D [1 ]
Scott, BL [1 ]
Nielsen, JB [1 ]
Abney, KD [1 ]
机构：
[1] Univ Calif Los Alamos Natl Lab, Chem Sci & Technol Div, Los Alamos, NM 87545 USA
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1999年 / 29卷 / 02期
关键词：
thorium; dimethoxyethane; crystal structure;
D O I：
10.1023/A:1009542715804
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The molecular structure of ThBr4(DME)(2) (DME = 1,2-dimethoxyethane), the first structurally characterized thorium complex containing a simple bidentate ether ligand, is described. The eight-coordinate complex presents a distorted dodecahedral geometry, with Th-Br and Th-O bond lengths in the ranges 2.8516(13)-2.8712(13) Angstrom and 2.564(8)-2.620(8) Angstrom, respectively. ThBr4(DME)(2) is monoclinic, space group P2(1)/n, a = 7.672(1), b = 14.581(1), c = 15.847(2) Angstrom, beta = 102.24(1)degrees, V = 1732.4(3) Angstrom(3), and Z = 4.
引用
收藏
页码：243 / 246
页数：4
相关论文
共 50 条
  • [1] Molecular structure of ThBr4(DME)2 (DME = 1,2-dimethoxyethane)
    Daniel Rabinovich
    Brian L. Scott
    Jon B. Nielsen
    Kent D. Abney
    [J]. Journal of Chemical Crystallography, 1999, 29 : 243 - 246
  • [2] Complexes of calcium halides with 1,2-dimethoxyethane (DME)
    Dell'Amico, DB
    Bradicich, C
    Labella, L
    Marchetti, F
    [J]. INORGANICA CHIMICA ACTA, 2006, 359 (05) : 1659 - 1665
  • [3] STRUCTURAL CHARACTERIZATION OF [LI(DME)PH2]INFINITY (DME = 1,2-DIMETHOXYETHANE) - PARENT OF THE LITHIUM DIORGANOPHOSPHIDES
    JONES, RA
    KOSCHMIEDER, SU
    NUNN, CM
    [J]. INORGANIC CHEMISTRY, 1987, 26 (21) : 3610 - 3611
  • [4] Crystal structure of the uranium oxo borohydride complex U2(μ-O)(BH4)6(dme)2 (dme=1,2-dimethoxyethane) and reformulation of U2(μ-H)2(BH4)6(dme)2
    Daly, Scott R.
    Ephritikhine, Michel
    Girolami, Gregory S.
    [J]. POLYHEDRON, 2012, 33 (01) : 41 - 44
  • [5] Insights into the oxidation kinetics of a cetane improver-1,2-dimethoxyethane (1,2-DME) with experimental and modeling methods
    Sun, Wenyu
    Lailliau, Maxence
    Serinyel, Zeynep
    Dayma, Guillaume
    Moshammer, Kai
    Hansen, Nils
    Yang, Bin
    Dagaut, Philippe
    [J]. PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2019, 37 (01) : 555 - 564
  • [6] TERT-BUO-SIME3, A FACILE OXYGEN-TRANSFER REAGENT - PREPARATION OF WOCL4, WOCL3DME, MOOCL3DME, [WOCL2DME]2O AND [MOOCL2DME]2O BY OXYGEN-TRANSFER REACTIONS (DME = 1,2-DIMETHOXYETHANE)
    PERSSON, C
    ANDERSSON, C
    [J]. POLYHEDRON, 1992, 11 (07) : 847 - 849
  • [7] Facile routes to sodium tetradecaphosphide Na4P14 and molecular structure of Na4(DME)7.5P14 and Na4(en)6P14 (DME=1,2-dimethoxyethane; en = ethylenediamine)
    Miluykov, Vasili
    Kataev, Alexander
    Sinyashin, Oleg
    Loennecke, Peter
    Hey-Hawkins, Evamarie
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (10-11): : 1728 - 1732
  • [8] Crystal and molecular structure of 1,2-dimethoxyethane crystallized on a new diffractometer
    Yokoyama, Y
    Uekusa, H
    Ohasi, Y
    [J]. CHEMISTRY LETTERS, 1996, (06) : 443 - 444
  • [9] SYNTHESIS AND CRYSTAL-STRUCTURE OF MOCL4(1,2-DIMETHOXYETHANE).15-CROWN-5 AND MOCL4(1,2-DIMETHOXYETHANE)
    HEYHAWKINS, E
    VONSCHNERING, HG
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (03): : 307 - 314
  • [10] 1,2-DIMETHOXYETHANE COMPLEXES OF MONCL3 AND WNCL3 - THE CRYSTAL-STRUCTURE OF [MONCL3-CENTER-DOT-DME]
    RENTSCHLER, E
    DEHNICKE, K
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1993, 48 (12): : 1841 - 1844
12345