1,2-DIMETHOXYETHANE COMPLEXES OF MONCL3 AND WNCL3 - THE CRYSTAL-STRUCTURE OF [MONCL3-CENTER-DOT-DME]

被引：7

作者：

RENTSCHLER, E ^{[1
]}

DEHNICKE, K ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1993年 / 48卷 / 12期

关键词：

DME COMPLEXES; NITRIDE CHLORIDES OF MOLYBDENUM AND TUNGSTEN; SYNTHESIS; CRYSTAL STRUCTURE;

D O I：

10.1515/znb-1993-1225

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [MoNCl3.DME] and [WNCl3.DME] (DME = 1,2-dimethoxyethane) have been prepared by the reaction of the nitride chlorides MNCl(3) with equimolar amounts of DME in CH2Cl2 suspensions. They form orange-red, moisture sensitive crystals, which are soluble in organic solvents. The molybdenum complex has been characterized by a crystal structure determination. Space group Pbca, Z = 8, structure solution with 1781 observed unique reflections, R = 0.031. Lattice dimensions at -60 degrees C: a = 738.6(1), b = 1182.2(1), c = 2314.1(1) pm. [MoNCl3 . DME] forms monomeric complexes with chelating DME molecules and Mo-O bond lengths of 215.4(4) and 247.4(4) pm, the longer one being in trans-position of the nitrido ligand. The MoN bond length of 163.3(5) pm suggests a triple bond.

引用

页码：1841 / 1844

页数：4

共 50 条

[1] COMPLEX CHEMICAL BEHAVIOR OF NITRIDE CHLORIDES MONCL3 AND WNCL3
KOLITSCH, W
DEHNICKE, K
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG PART B-CHEMIE BIOCHEMIE BIOPHYSIK BIOLOGIE UND VERWANDTEN GEBIETE, 1970, B 25 (10): : 1080 - &
[2] CRYSTAL STRUCTURE OF MOLYBDENUM NITRIDE TRICHLORIDE, MONCL3
STRAHLE, J
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1969, 8 (11) : 925 - &
[3] Syntheses and crystal structures of the nitrido complexes [MoNCl3(MeCN)]4 and (MoNCl2(bipy)]4
Gauch, E
Hagenbach, A
Strähle, J
Dietrich, A
Neumüller, B
Dehnicke, K
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (02): : 489 - 493
[4] PREPARATION, CRYSTAL-STRUCTURE AND INFRARED-SPECTRUM OF [MONCL3 POCL3]4
STRAHLE, J
WEIHER, U
DEHNICKE, K
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1978, 33 (11): : 1347 - 1351
[5] CRYSTAL AND MOLECULAR STRUCTURE OF DIBROMO-BIS(1,2 DIMETHOXYETHANE) TITANIUM(3) TETRABROMO(1,2-DIMETHOXYETHANE) TITANATE(3)
FOWLES, GWA
LESTER, TE
WOOD, JS
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1969, 31 (03): : 657 - &
[6] Reactions of MoNCl3 and WNCL(3) with elemental fluorine. Crystal structures of [MoO2F2(THF)(2)] and [WF4(NCl)(CH3CN)]
Rhiel, M
Wocadlo, S
Massa, W
Dehnicke, K
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (07): : 1195 - 1199
[7] 1,4-DILITHIO-1,2,3,4-TETRAPHENYL-BUTADIENE - CRYSTAL-STRUCTURE OF THE 1,2-DIMETHOXYETHANE ADDUCT
PAUER, F
POWER, PP
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 474 (1-2) : 27 - 30
[8] MOLYBDENUMNITRIDETRICHLORIDE-2,3,3-TRICHLOROACRYLNITRILE, [MONCL3.NC-C2CL3]2 SYNTHESIS, IR-SPECTRUM, AND CRYSTAL-STRUCTURE
KHABOU, A
DEHNICKE, K
FINDEISEN, K
FENSKE, D
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1988, 43 (12): : 1616 - 1620
[9] SYNTHESIS, IR AND ELECTRON-PARAMAGNETIC-RES SPECTRA, AND CRYSTAL-STRUCTURE OF (PPH3ME)2[MONCL4]
SCHMITTE, J
FRIEBEL, C
WELLER, F
DEHNICKE, K
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1982, 495 (12): : 148 - 156
[10] REACTION OF KSI WITH M(CO)6 (M = CR, MO, W) AND CR(CO)5NME3 - CRYSTAL-STRUCTURE OF [K(DME)2]2[CR2(CO)10] (DME = 1,2-DIMETHOXYETHANE)
HEYHAWKINS, E
VONSCHNERING, HG
[J]. CHEMISCHE BERICHTE, 1991, 124 (05) : 1167 - 1169

← 1 2 3 4 5 →