Facile routes to sodium tetradecaphosphide Na4P14 and molecular structure of Na4(DME)7.5P14 and Na4(en)6P14 (DME=1,2-dimethoxyethane; en = ethylenediamine)

被引：22
|
作者：
Miluykov, Vasili
Kataev, Alexander
Sinyashin, Oleg
Loennecke, Peter
Hey-Hawkins, Evamarie
机构：
[1] Russian Acad Sci, E Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia
[2] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2006年 / 632卷 / 10-11期
关键词：
phosphorus; NMR (P-31) spectroscopy; tetradecaphosphide;
D O I：
10.1002/zaac.200600108
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tetrasodium tetradecaphosphide Na4P14 was obtained either from the reaction of PCl3 with sodium in refluxing THF or from the reaction of red phosphorus and sodium in ethylenediamine at room temperature. The solid-state structures of Na-4(DME)(7.5)P-14 (1a) and Na-4(en)(6)P-14 (1b) (DME = 1,2-dimethoxyethane; en = ethylenediamine) are described.
引用
收藏
页码：1728 / 1732
页数：5
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