Facile routes to sodium tetradecaphosphide Na4P14 and molecular structure of Na4(DME)7.5P14 and Na4(en)6P14 (DME=1,2-dimethoxyethane; en = ethylenediamine)

被引：22

作者：

Miluykov, Vasili

Kataev, Alexander

Sinyashin, Oleg

Loennecke, Peter

Hey-Hawkins, Evamarie

机构：

[1] Russian Acad Sci, E Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia

[2] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2006年 / 632卷 / 10-11期

关键词：

phosphorus; NMR (P-31) spectroscopy; tetradecaphosphide;

D O I：

10.1002/zaac.200600108

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetrasodium tetradecaphosphide Na4P14 was obtained either from the reaction of PCl3 with sodium in refluxing THF or from the reaction of red phosphorus and sodium in ethylenediamine at room temperature. The solid-state structures of Na-4(DME)(7.5)P-14 (1a) and Na-4(en)(6)P-14 (1b) (DME = 1,2-dimethoxyethane; en = ethylenediamine) are described.

引用

页码：1728 / 1732

页数：5

共 23 条

[21] Crystal structure of 9-benzoyl-5-methoxy-7-phenyl-7-phthalimido-2,2,3,3-tetramethyl-1,4,6-trioxa-5-phospha(V)spiro[4,4]non-8-en, C62H60N2O14P2 and of dimethyl 3-(4,4,4′,4′,5,5,5′,5′-octamethyl-1,1′,3,3′-tetraoxa-2-phospha(V)-spiro[4,4]nonanyl)-2(N,N-dimethyl)succinate), C20H38NO8P, two tetraoxaspiro-phosphorane(V) intermediates
Neuman, A
Leroux, Y
El Manouni, D
Prangé, T
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2000, 215 (04): : 539 - 543
[22] PI-GROUPS IN ION-PAIR BONDING - MOLECULAR STRUCTURE OF BIS(TETRAHYDROFURAN)SODIUM (9,10-DIHYDRO-9,10-ANTHRYLENE)DIMETHYLALUMINATE [NA)C4H8O)2]2[A1(CH3)2C14H10]2,A SODIUM-TRIMETHYLALUMINUM REDUCTION PRODUCT OF ANTHRACENE
BRAUER, DJ
STUCKY, GD
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 37 (02) : 217 - &
[23] Polynuclear complexes with bridging pyrophosphate ligands:: synthesis and characterisation of {[(bipy)Cu(H2O)(μ-P2O7)Na2(H2O)6]•4H2O}, {[(bipy)Zn-(H2O)(μ-P2O7)Zn(bipy)]2•14H2O} and {[(bipy)(VO)2]2(μ-P2O7)]•5H2O}
Doyle, RP
Nieuwenhuyzen, M
Kruger, PE
[J]. DALTON TRANSACTIONS, 2005, (23) : 3745 - 3750

← 1 2 3 →