Copper-catalyzed asymmetric alkylation of imines with dialkylzinc and related reactions

被引：252
|
作者：
Yamada, Ken-ichi [1 ]
Tomioka, Kiyoshi [1 ]
机构：
[1] Kyoto Univ, Grad Sch Pharmaceut Sci, Kyoto 6068501, Japan
来源：
CHEMICAL REVIEWS | 2008年 / 108卷 / 08期
关键词：
D O I：
10.1021/cr078370u
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A focus on the recently developed copper-catalyzed asymmetric reactions and some related reactions are presented. Also included in the report are the copper-catalyzed asymmetric allylation, arylation, and alkynylation of imines; catalysts for asymmetric alkylation of imines with diorganozinc reagents; and the incorporation of radical pathways. Further development in the field of dialkylzinc reagents will provide a convenient approach to a variety of chiral nitrogen-containing molecules.
引用
收藏
页码：2874 / 2886
页数：13
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