Copper-catalyzed asymmetric alkylation of imines with dialkylzinc and related reactions

被引：252
|
作者：
Yamada, Ken-ichi [1 ]
Tomioka, Kiyoshi [1 ]
机构：
[1] Kyoto Univ, Grad Sch Pharmaceut Sci, Kyoto 6068501, Japan
来源：
CHEMICAL REVIEWS | 2008年 / 108卷 / 08期
关键词：
D O I：
10.1021/cr078370u
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A focus on the recently developed copper-catalyzed asymmetric reactions and some related reactions are presented. Also included in the report are the copper-catalyzed asymmetric allylation, arylation, and alkynylation of imines; catalysts for asymmetric alkylation of imines with diorganozinc reagents; and the incorporation of radical pathways. Further development in the field of dialkylzinc reagents will provide a convenient approach to a variety of chiral nitrogen-containing molecules.
引用
收藏
页码：2874 / 2886
页数：13
相关论文
共 50 条
  • [31] Copper-catalyzed asymmetric propargylic substitution reactions of propargylic acetates with amines
    Hattori, Gaku
    Matsuzawa, Hiroshi
    Miyake, Yoshihiro
    Nishibayashi, Yoshiaki
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (20) : 3781 - 3783
  • [32] Copper-catalyzed asymmetric allylic substitution reactions with organozinc and Grignard reagents
    Geurts, Koen
    Fletcher, Stephen P.
    van Zijl, Anthoni W.
    Minnaard, Adriaan J.
    Feringa, Ben L.
    PURE AND APPLIED CHEMISTRY, 2008, 80 (05) : 1025 - 1037
  • [33] Copper-catalyzed steroid reactions
    Ibrahim-Ouali, Malika
    Dumur, Frederic
    ARKIVOC, 2017, : 202 - 256
  • [34] Copper-catalyzed multicomponent reactions
    Chen, Joanna L.
    Namirembe, Sheila
    Isaacs, Andre K.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [35] Copper-Catalyzed Reactions of Alkylboranes
    Ohmiya, Hirohisa
    Sawamura, Masaya
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2021, 94 (01) : 197 - 203
  • [36] Mechanistic identification and improvement of a direct enantioconvergent transformation in copper-catalyzed asymmetric allylic alkylation
    Langlois, Jean-Baptiste
    Emery, Daniel
    Mareda, Jiri
    Alexakis, Alexandre
    CHEMICAL SCIENCE, 2012, 3 (04) : 1062 - 1069
  • [37] Copper-Catalyzed Asymmetric Allyl Alkylation Using Grignard Reagents under Continuous Flow
    Song Xiao
    Qing Jing
    Li Jun
    Jia Xuelei
    Wu Fusong
    Huang Junrong
    Jin Jian
    You Hengzhi
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2023, 43 (09) : 3174 - 3179
  • [38] Copper-Catalyzed Coupling Reactions
    Rao, Honghua
    Fu, Hua
    SYNLETT, 2011, (06) : 745 - 769
  • [39] Copper-Catalyzed Asymmetric Allylic Alkylation of Racemic Cyclic Allyl Bromides with Organolithium Compounds
    Li, Jun
    Song, Xiao
    Wu, Fusong
    You, Hengzhi
    Chen, Fen-Er
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 2022 (34)
  • [40] Copper-Catalyzed Alkylation of Thiophenols with Benzyltrimethylammonium Triflates
    Lu, Fangling
    Chen, Ziyue
    Li, Zhen
    Wang, Xiaoyan
    Peng, Xinyue
    Li, Cong
    Li, Ru
    Pei, Hongqiao
    Wang, Huamin
    Gao, Meng
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 7 (01) : 141 - 144
12345