Palladium-catalyzed aminocarbonylation of aryl iodides with amines: efficient access to bidentate amide directing groups

被引：3
|
作者：
Wang, Yanqing [1 ]
Wang, Tao [2 ]
Wang, Xiaosha [2 ]
Liu, Lantao [2 ,3 ]
Mao, Guoliang [1 ]
机构：
[1] Northeast Petr Univ, Coll Chem & Chem Engn, Daqing 163318, Peoples R China
[2] Shangqiu Normal Univ, Henan Engn Lab Green Synth Pharmaceut, Coll Chem & Chem Engn, Shangqiu 476000, Peoples R China
[3] Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 2021年 / 46卷 / 01期
关键词：
C-H BONDS; C(SP(2))-H BONDS; SELECTIVE ACCESS; C(SP(3))-H BONDS; AROMATIC AMIDES; AMINATION; FUNCTIONALIZATION; ALKYNYLATION; DERIVATIVES; ANNULATION;
D O I：
10.1007/s11243-020-00418-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new route to bidentate amide directing groups has been developed via the palladium(II)-catalyzed aminocarbonylation. Under atmospheric carbon monoxide pressure, using commercially available aryl iodides and aromatic amine derivatives as substrates, the three-component reaction proceeded smoothly to give the desired products in moderate-to-excellent yields with good functional-group compatibility.
引用
收藏
页码：29 / 35
页数：7
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