Palladium-catalyzed aminocarbonylation of aryl iodides with amines: efficient access to bidentate amide directing groups

被引：3

作者：

Wang, Yanqing ^{[1
]}

Wang, Tao ^{[2
]}

Wang, Xiaosha ^{[2
]}

Liu, Lantao ^{[2
,3
]}

Mao, Guoliang ^{[1
]}

机构：

[1] Northeast Petr Univ, Coll Chem & Chem Engn, Daqing 163318, Peoples R China

[2] Shangqiu Normal Univ, Henan Engn Lab Green Synth Pharmaceut, Coll Chem & Chem Engn, Shangqiu 476000, Peoples R China

[3] Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2021年 / 46卷 / 01期

关键词：

C-H BONDS; C(SP(2))-H BONDS; SELECTIVE ACCESS; C(SP(3))-H BONDS; AROMATIC AMIDES; AMINATION; FUNCTIONALIZATION; ALKYNYLATION; DERIVATIVES; ANNULATION;

D O I：

10.1007/s11243-020-00418-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new route to bidentate amide directing groups has been developed via the palladium(II)-catalyzed aminocarbonylation. Under atmospheric carbon monoxide pressure, using commercially available aryl iodides and aromatic amine derivatives as substrates, the three-component reaction proceeded smoothly to give the desired products in moderate-to-excellent yields with good functional-group compatibility.

引用

页码：29 / 35

页数：7

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