Conformational dependence of the first molecular hyperpolarizability in the computational design of nonlinear optical materials for optical switching

被引：45

作者：

Suponitsky, Kyrill Yu. ^{[1
,2
]}

Masunov, Artem E. ^{[2
]}

Antipin, Mikhail Yu. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

[2] Univ Cent Florida, Nanosci Technol Ctr, Orlando, FL 32826 USA

来源：

MENDELEEV COMMUNICATIONS | 2008年 / 18卷 / 05期

基金：

俄罗斯基础研究基金会; 美国国家科学基金会;

关键词：

D O I：

10.1016/j.mencom.2008.09.013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In certain cases for conjugated molecules, which can often be found in several conformations close in energy, hyperpolarizabilities of the rotamers differ by less than 20%, which is comparable to uncertainty in experimental data and this makes it possible to consider only one representative conformation in the process of computational design.

引用

页码：265 / 267

页数：3

共 50 条

[41] Determination of first hyperpolarizability of nonlinear optical chromophores by second harmonic scattering using an external reference
Pauley, MA
Guan, HW
Wang, CH
Jen, AKY
JOURNAL OF CHEMICAL PHYSICS, 1996, 104 (20): : 7821 - 7829
[42] π-Bridging 1,3-heterocyclic aromatic rings and the first hyperpolarizability of nonlinear optical compounds
Ra, CS
Kim, SC
Park, G
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2004, 677 (1-3): : 173 - 178
[43] Design of cascaded plasmon resonances for ultrafast nonlinear optical switching
Toroghi, S.
Kik, P. G.
ENABLING PHOTONICS TECHNOLOGIES FOR DEFENSE, SECURITY, AND AEROSPACE APPLICATIONS VII, 2011, 8054
[44] Nonlinear optical switching matrix
Liu, GJ
Liu, J
Liang, BM
Li, Q
Lin, GL
OPTICS LETTERS, 2003, 28 (15) : 1347 - 1349
[45] NONLINEAR OPTICAL ANALYSIS OF A SERIES OF TRIBLOCK COPOLYMERS CONTAINING MODEL POLYENES - THE DEPENDENCE OF HYPERPOLARIZABILITY ON CONJUGATION LENGTH
CRAIG, GSW
COHEN, RE
SCHROCK, RR
SILBEY, RJ
PUCCETTI, G
LEDOUX, I
ZYSS, J
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (03) : 860 - 867
[46] Design of organic molecules and materials for nonlinear optical applications
Marder, Seth
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
[47] DESIGN AND SYNTHESIS OF ORGANIC NONLINEAR OPTICAL-MATERIALS
HUTCHINGS, MG
GORDON, PF
MORLEY, JO
INSTITUTE OF PHYSICS CONFERENCE SERIES, 1989, (103): : 97 - 106
[48] DESIGN AND SYNTHESIS OF ORGANIC NONLINEAR OPTICAL-MATERIALS
HUTCHINGS, MG
GORDON, PF
MORLEY, JO
MATERIALS FOR NON-LINEAR AND ELECTRO-OPTICS 1989, 1989, 103 : 97 - 106
[49] NONLINEAR OPTICAL MATERIALS
BERGMAN, JG
KURTZ, SK
MATERIALS SCIENCE AND ENGINEERING, 1970, 5 (05): : 235 - +
[50] NONLINEAR OPTICAL MATERIALS
SUVOROV, VS
SONIN, AS
SOVIET PHYSICS CRYSTALLOGRAPHY, USSR, 1967, 11 (05): : 711 - +

← 1 2 3 4 5 →