Allyl rhodium(III) complexes containing heterocyclic nitrogen ligands

被引：2
|
作者：
Pasternak, H [1 ]
Pruchnik, FP [1 ]
机构：
[1] WROCLAW B BEIRUT UNIV,INST CHEM,PL-50383 WROCLAW,POLAND
来源：
TRANSITION METAL CHEMISTRY | 1996年 / 21卷 / 04期
关键词：
D O I：
10.1007/BF00139023
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of hexacoordinated Rh-III complexes of general formula trans-[RhCl2(allyl)(N-N)] (allyl = C3H5 or C4H7; N-N = 1,10-phenanthroline, 2,9-dimethyl-1,10-phenanthroline, 4,7-diphenyl-1,10-phenanthroline, 2,2'-bipyridine or 4,4'-dimethyl-2,2'-bipyridine) have been synthesized and characterized by spectroscopic methods. The complexes have an octahedral geometry with the Cl ligands coordinated in the trans positions. The catalytic activity of [RhCl2(C4H7)(phen)] with respect to hydrogenation of alkenes has been investigated.
引用
收藏
页码：305 / 308
页数：4
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