Enhancement of photoluminescence properties of CaAl2Si2O8:Eu2+ by SiO2 addition

被引:7
|
作者
Kim, B. S. [1 ]
Song, Y. H. [1 ]
Jo, D. S. [1 ]
Abe, T. [2 ]
Senthil, K. [1 ]
Masaki, T. [1 ]
Toda, K. [2 ]
Yoon, D. H. [1 ,3 ]
机构
[1] Sungkyunkwan Univ, Sch Adv Mat Sci & Engn, Suwon 440746, South Korea
[2] Niigata Univ, Fac Engn, Dept Chem & Chem Engn, Niigata 9502181, Japan
[3] Sungkyunkwan Univ, SKKU Adv Inst Nanotechnol SAINT, Suwon 440746, South Korea
关键词
Optical materials; X-ray diffraction; Luminescence; Optical properties; LIGHT-EMITTING-DIODES; LUMINESCENT PROPERTIES; OPTICAL-PROPERTIES; PHOSPHOR; GREEN; EMISSION;
D O I
10.1016/j.materresbull.2012.04.109
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
SiO2 added phosphors, CaAl2Si2O8:Eu2+ + xSiO(2) (x = 0, 1, 2, 3, 4, 5, 6 and 13 mol) were synthesized by a novel liquid phase precursor (LPP) method. The photoluminescence properties of phosphor added by 5 mol of SiO2 showed 110% enhancement in the emission intensity compared to the CaAl2Si2O8:Eu2+ phosphor. A broad emission and excitation wavelength was observed approximately from 400 nm to 600 nm centered at 430 nm and from 280 nm to 400 nm centered at 365 nm, respectively. Photoluminescence intensity of the phosphors increased continuously by SiO2 addition up to x = 5 mol and then it decreased with further addition of SiO2. The observed photoluminescence properties of the phosphors were discussed related to their crystalline structure and morphology. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3015 / 3019
页数:5
相关论文
共 50 条
  • [41] The binary system Na2Al2Si2O8 (Nephelite, carnegieite) - CaAl2Si2O8 (Anorthite)
    Bowen, NL
    AMERICAN JOURNAL OF SCIENCE, 1912, 33 (198) : 551 - 573
  • [42] Sr2+ substitution for Ca2+ and Eu2+,Dy3+ co-doping enhance mechanoluminescence of CaAl2Si2O8 phosphors
    Fang, Hua
    Qiu, Gaojian
    Li, Jun
    Wang, Xusheng
    JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 763 : 267 - 272
  • [43] Mechanical Properties of CaO-Al2O3-SiO2 Glass-Ceramics Precipitating Hexagonal CaAl2Si2O8 Crystals
    Maeda, Kei
    Akatsuka, Kosho
    Okuma, Gaku
    Yasumori, Atsuo
    CRYSTALS, 2021, 11 (04):
  • [44] Molecular dynamics simulations of molten CaAl2Si2O8:: Dependence of structure and properties on pressure
    Nevins, D
    Spera, FJ
    AMERICAN MINERALOGIST, 1998, 83 (11-12) : 1220 - 1230
  • [45] Fabrication and Photoluminescence Properties of Monodispersed SiO2@ SrAl2Si2O8: Eu2+ Core-Shell Submicron Spheres
    Zhang, J. M.
    Zhao, D. L.
    Zhang, D. D.
    Shen, Z. M.
    ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (08) : 2211 - 2214
  • [46] Single-phased white-light emitting CaAl2Si2O8: Eu2+, Mn2+ phosphors prepared by a sol–gel method
    Baoling Wang
    Liuzheng Sun
    Haidong Ju
    Shilong Zhao
    Degang Deng
    Huanping Wang
    Shiqing Xu
    Journal of Sol-Gel Science and Technology, 2009, 50 : 368 - 371
  • [47] Structure of crystalline CaAl2Si2O8 precipitated in a CaO-Al2O3-SiO2 glass-ceramic
    Akatsuka, Kosho
    Yasumori, Atsuo
    Maeda, Kei
    MATERIALS LETTERS, 2019, 242 : 163 - 165
  • [48] Influence of flux on morphological & optical properties of RE doped CaAl2Si2O8 phosphor
    Kailuke, M. S.
    Pawade, V. B.
    Dhoble, S. J.
    OPTICAL MATERIALS, 2024, 151
  • [49] Study of photoluminescence properties of CaAl2O4: Eu2+ prepared by combustion synthesis method
    Hingwe, V. S.
    Bajaj, N. S.
    Omanwar, S. K.
    INTERNATIONAL CONFERENCE ON CONDENSED MATTER AND APPLIED PHYSICS (ICC 2015), 2016, 1728
  • [50] Preparation and luminescence properties of Eu2+ in SiO2 xerogels
    Hu, Xiaoyun
    Fan, Jun
    Li, Ting
    Zhang, Dekal
    Chen, Weizong
    Bai, Jintao
    Hou, Xun
    OPTICAL MATERIALS, 2007, 29 (11) : 1327 - 1331