Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus

被引：58

作者：

Wild, Stefan ^{[1
,2
,3
]}

Fickert, Michael ^{[1
,2
,3
]}

Mitrovic, Aleksandra ^{[1
,2
,3
]}

Lloret, Vicent ^{[1
,2
,3
]}

Neiss, Christian ^{[4
,5
]}

Vidal-Moya, Jose Alejandro ^{[6
]}

Rivero-Crespo, Miguel Angel ^{[6
]}

Leyva-Perez, Antonio ^{[6
]}

Werbach, Katharina ^{[7
]}

Peterlik, Herwig ^{[7
]}

Grabau, Mathias ^{[8
]}

Wittkaemper, Haiko ^{[8
]}

Papp, Christian ^{[8
]}

Steinrueck, Hans-Peter ^{[8
]}

Pichler, Thomas ^{[7
]}

Goerling, Andreas ^{[4
,5
]}

Hauke, Frank ^{[1
,2
,3
]}

Abellan, Gonzalo ^{[1
,2
,3
,9
]}

Hirsch, Andreas ^{[1
,2
,3
]}

机构：

[1] Friedrich Alexander Univ Erlangen Nurnberg FAU, Chair Organ Chem 2, Nikolaus Fiebiger Str 10, D-91058 Erlangen, Germany

[2] Friedrich Alexander Univ Erlangen Nurnberg FAU, Joint Inst Adv Mat & Proc ZMP, Nikolaus Fiebiger Str 10, D-91058 Erlangen, Germany

[3] Dr Mack Str 81, D-90762 Furth, Germany

[4] Friedrich Alexander Univ Erlangen Nurnberg FAU, Lehrstuhl Theoret Chem, Egerlandstr 3, D-91058 Erlangen, Germany

[5] Friedrich Alexander Univ Erlangen Nurnberg FAU, ICMM, Egerlandstr 3, D-91058 Erlangen, Germany

[6] Univ Politecn Valencia, CSIC, Inst Tecnol & Quim, Avda Naranjos S-N, E-46022 Valencia, Spain

[7] Univ Vienna, Fac Phys, Strudlhofgasse 4, A-1090 Vienna, Austria

[8] FAU, Lehrstuhl Phys Chem 2, Egerlandstr 3, D-91058 Erlangen, Germany

[9] Univ Valencia, Inst Ciencia Mol ICMol, Catedrat Jose Beltran 2, Valencia 46980, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 17期

基金：

欧洲研究理事会;

关键词：

P-31 NMR spectroscopy; black phosphorus; covalent functionalization; Raman spectroscopy; reductive route; PASSIVATION;

D O I：

10.1002/anie.201811181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.

引用

页码：5763 / 5768

页数：6

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