Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus

被引：58

作者：

Wild, Stefan ^{[1
,2
,3
]}

Fickert, Michael ^{[1
,2
,3
]}

Mitrovic, Aleksandra ^{[1
,2
,3
]}

Lloret, Vicent ^{[1
,2
,3
]}

Neiss, Christian ^{[4
,5
]}

Vidal-Moya, Jose Alejandro ^{[6
]}

Rivero-Crespo, Miguel Angel ^{[6
]}

Leyva-Perez, Antonio ^{[6
]}

Werbach, Katharina ^{[7
]}

Peterlik, Herwig ^{[7
]}

Grabau, Mathias ^{[8
]}

Wittkaemper, Haiko ^{[8
]}

Papp, Christian ^{[8
]}

Steinrueck, Hans-Peter ^{[8
]}

Pichler, Thomas ^{[7
]}

Goerling, Andreas ^{[4
,5
]}

Hauke, Frank ^{[1
,2
,3
]}

Abellan, Gonzalo ^{[1
,2
,3
,9
]}

Hirsch, Andreas ^{[1
,2
,3
]}

机构：

[1] Friedrich Alexander Univ Erlangen Nurnberg FAU, Chair Organ Chem 2, Nikolaus Fiebiger Str 10, D-91058 Erlangen, Germany

[2] Friedrich Alexander Univ Erlangen Nurnberg FAU, Joint Inst Adv Mat & Proc ZMP, Nikolaus Fiebiger Str 10, D-91058 Erlangen, Germany

[3] Dr Mack Str 81, D-90762 Furth, Germany

[4] Friedrich Alexander Univ Erlangen Nurnberg FAU, Lehrstuhl Theoret Chem, Egerlandstr 3, D-91058 Erlangen, Germany

[5] Friedrich Alexander Univ Erlangen Nurnberg FAU, ICMM, Egerlandstr 3, D-91058 Erlangen, Germany

[6] Univ Politecn Valencia, CSIC, Inst Tecnol & Quim, Avda Naranjos S-N, E-46022 Valencia, Spain

[7] Univ Vienna, Fac Phys, Strudlhofgasse 4, A-1090 Vienna, Austria

[8] FAU, Lehrstuhl Phys Chem 2, Egerlandstr 3, D-91058 Erlangen, Germany

[9] Univ Valencia, Inst Ciencia Mol ICMol, Catedrat Jose Beltran 2, Valencia 46980, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 17期

基金：

欧洲研究理事会;

关键词：

P-31 NMR spectroscopy; black phosphorus; covalent functionalization; Raman spectroscopy; reductive route; PASSIVATION;

D O I：

10.1002/anie.201811181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.

引用

页码：5763 / 5768

页数：6

共 50 条

[21] Covalent functionalization of black phosphorus nanoflakes by carbon free radicals for durable air and water stability
Hu, Haiguo
Gao, Hong
Gao, Lili
Li, Feng
Xu, Na
Long, Xuefeng
Hu, Yiping
Jin, Jun
Ma, Jiantai
NANOSCALE, 2018, 10 (13) : 5834 - 5839
[22] Covalent functionalization of black phosphorus nanosheets via insensitive glycidyl azide polymer with durable stability
Li, Shengnan
Jiao, Yuke
Ding, Shanjun
Yang, Desheng
Niu, Ziteng
Li, Guoping
Wang, Xiaoqing
Luo, Yunjun
JOURNAL OF MATERIALS SCIENCE, 2022, 57 (36) : 17265 - 17276
[23] Covalent functionalization of black phosphorus nanosheets via insensitive glycidyl azide polymer with durable stability
Shengnan Li
Yuke Jiao
Shanjun Ding
Desheng Yang
Ziteng Niu
Guoping Li
Xiaoqing Wang
Yunjun Luo
Journal of Materials Science, 2022, 57 : 17265 - 17276
[24] Upon Not Opening The Black Box
Gahoonia, Simy Kaur
Ferreira, Pedro
Cohn, Marisa
Henriksen, Line
Kjaer, Katrine Meldgaard
Hockenhull, Michael
Cakici, Baki
Blond, Marie
Douglas-Jones, Rachel
Laursen, Caecilie Sloth
Zell, Sonja
CHI'20: EXTENDED ABSTRACTS OF THE 2020 CHI CONFERENCE ON HUMAN FACTORS IN COMPUTING SYSTEMS, 2020,
[25] Covalent functionalization of boron nitride nanosheets via reductive activation
Sun, Changjiu
Zhao, Jian
Zhang, Deli
Guo, Hongge
Wang, Xin
Hu, Haiqing
NANOSCALE, 2020, 12 (35) : 18379 - 18389
[26] Carbon Nano-onions: Potassium Intercalation and Reductive Covalent Functionalization
Perez-Ojeda, M. Eugenia
Castro, Edison
Kroeckel, Claudia
Lucherelli, Matteo Andrea
Ludacka, Ursula
Kotakoski, Jani
Werbach, Katharina
Peterlik, Herwig
Melle-Franco, Manuel
Chacon-Torres, Julio C.
Hauke, Frank
Echegoyen, Luis
Hirsch, Andreas
Abellan, Gonzalo
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (45) : 18997 - 19007
[27] New insights into the covalent functionalization of black and blue phosphorene
Denis, Pablo A.
COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2022, 1215
[28] Covalent functionalized black phosphorus quantum dots
Scotognella, Francesco
Kriegel, Ilka
Sassolini, Simone
OPTICAL MATERIALS, 2018, 75 : 521 - 524
[29] LATTICE-DYNAMICS OF BLACK PHOSPHORUS
MORITA, A
KANETA, C
KATAYAMAYOSHIDA, H
PHYSICA B & C, 1983, 117 (MAR): : 517 - 519
[30] LATTICE-DYNAMICS OF BLACK PHOSPHORUS
KANETA, C
KATAYAMAYOSHIDA, H
MORITA, A
SOLID STATE COMMUNICATIONS, 1982, 44 (05) : 613 - 617

← 1 2 3 4 5 →