Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus

被引：58

作者：

Wild, Stefan ^{[1
,2
,3
]}

Fickert, Michael ^{[1
,2
,3
]}

Mitrovic, Aleksandra ^{[1
,2
,3
]}

Lloret, Vicent ^{[1
,2
,3
]}

Neiss, Christian ^{[4
,5
]}

Vidal-Moya, Jose Alejandro ^{[6
]}

Rivero-Crespo, Miguel Angel ^{[6
]}

Leyva-Perez, Antonio ^{[6
]}

Werbach, Katharina ^{[7
]}

Peterlik, Herwig ^{[7
]}

Grabau, Mathias ^{[8
]}

Wittkaemper, Haiko ^{[8
]}

Papp, Christian ^{[8
]}

Steinrueck, Hans-Peter ^{[8
]}

Pichler, Thomas ^{[7
]}

Goerling, Andreas ^{[4
,5
]}

Hauke, Frank ^{[1
,2
,3
]}

Abellan, Gonzalo ^{[1
,2
,3
,9
]}

Hirsch, Andreas ^{[1
,2
,3
]}

机构：

[1] Friedrich Alexander Univ Erlangen Nurnberg FAU, Chair Organ Chem 2, Nikolaus Fiebiger Str 10, D-91058 Erlangen, Germany

[2] Friedrich Alexander Univ Erlangen Nurnberg FAU, Joint Inst Adv Mat & Proc ZMP, Nikolaus Fiebiger Str 10, D-91058 Erlangen, Germany

[3] Dr Mack Str 81, D-90762 Furth, Germany

[4] Friedrich Alexander Univ Erlangen Nurnberg FAU, Lehrstuhl Theoret Chem, Egerlandstr 3, D-91058 Erlangen, Germany

[5] Friedrich Alexander Univ Erlangen Nurnberg FAU, ICMM, Egerlandstr 3, D-91058 Erlangen, Germany

[6] Univ Politecn Valencia, CSIC, Inst Tecnol & Quim, Avda Naranjos S-N, E-46022 Valencia, Spain

[7] Univ Vienna, Fac Phys, Strudlhofgasse 4, A-1090 Vienna, Austria

[8] FAU, Lehrstuhl Phys Chem 2, Egerlandstr 3, D-91058 Erlangen, Germany

[9] Univ Valencia, Inst Ciencia Mol ICMol, Catedrat Jose Beltran 2, Valencia 46980, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 17期

基金：

欧洲研究理事会;

关键词：

P-31 NMR spectroscopy; black phosphorus; covalent functionalization; Raman spectroscopy; reductive route; PASSIVATION;

D O I：

10.1002/anie.201811181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.

引用

页码：5763 / 5768

页数：6

共 50 条

[1] Quantifying the Covalent Functionalization of Black Phosphorus
Wild, Stefan
Xuan Thong Dinh
Maid, Harald
Hauke, Frank
Abellan, Gonzalo
Hirsch, Andreas
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (45) : 20230 - 20234
[2] The Covalent Functionalization of Layered Black Phosphorus by Nucleophilic Reagents
Sofer, Zdenek
Luxa, Jan
Bousa, Daniel
Sedmidubsky, David
Lazar, Petr
Hartman, Tomas
Hardtdegen, Hilde
Pumera, Martin
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (33) : 9891 - 9896
[3] One-Pot Covalent Functionalization of 2D Black Phosphorus by Anionic Ring Opening Polymerization
Bawadkji, Obida
Cherri, Mariam
Schaefer, Andreas
Herziger, Svenja
Nickl, Philip
Achazi, Katharina
Donskyi, Ievgen S.
Adeli, Mohsen
Haag, Rainer
ADVANCED MATERIALS INTERFACES, 2022, 9 (32):
[4] Covalent Functionalization of Black Phosphorus from First-Principles
Li, Qiang
Zhou, Qionghua
Niu, Xianghong
Zhao, Yinghe
Chen, Qian
Wang, Jinlan
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2016, 7 (22): : 4540 - 4546
[5] Stabilizing Black Phosphorus via Covalent Functionalization of Solvent Formamide
He, Zuoliang
Liu, Rui
Shan, Wanyu
Zhao, Huachao
Lai, Yujian
Li, Peng
Liu, Jingfu
ADVANCED MATERIALS INTERFACES, 2021, 8 (11)
[6] Covalent Functionalization of Black Phosphorus with Conjugated Polymer for Information Storage
Cao, Yaming
Tian, Xiangyu
Gu, Junwei
Liu, Bo
Zhang, Bin
Song, Sannian
Fan, Fei
Chen, Yu
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (17) : 4543 - 4548
[7] Covalent bulk functionalization of graphene
Englert, Jan M.
Dotzer, Christoph
Yang, Guang
Schmid, Martin
Papp, Christian
Gottfried, J. Michael
Steinrueck, Hans-Peter
Spiecker, Erdmann
Hauke, Frank
Hirsch, Andreas
NATURE CHEMISTRY, 2011, 3 (04) : 279 - 286
[8] Covalent bulk functionalization of graphene
Englert J.M.
Dotzer C.
Yang G.
Schmid M.
Papp C.
Gottfried J.M.
Steinrück H.-P.
Spiecker E.
Hauke F.
Hirsch A.
Nature Chemistry, 2011, 3 (4) : 279 - 286
[9] Covalent Functionalization of Few-Layer Black Phosphorus Using lodonium Salts and Comparison to Diazonium Modified Black Phosphorus
van Druenen, Maart
Davitt, Fionan
Collins, Timothy
Glynn, Colm
O'Dwyer, Colm
Holmes, Justin D.
Collins, Gillian
CHEMISTRY OF MATERIALS, 2018, 30 (14) : 4667 - 4674
[10] Unifying Principles of the Reductive Covalent Graphene Functionalization
Abellan, Gonzalo
Schirowski, Milan
Edelthalhammer, Konstantin F.
Fickert, Michael
Werbach, Katharina
Peterlik, Herwig
Hauke, Frank
Hirsch, Andreas
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (14) : 5175 - 5182

← 1 2 3 4 5 →