Convenient synthesis of aliphatic (CF3)2N-compounds

被引：4

作者：

Breitenstein, Christoph ^{[1
]}

Ignat'ev, Nikolai ^{[2
]}

Frank, Walter ^{[1
]}

机构：

[1] Heinrich Heine Univ, Inst Anorgan Chem & Strukturchem Mat & Strukturfo, Dusseldorf, Germany

[2] Merck KGaA, Darmstadt, Germany

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2018年 / 210卷

关键词：

Nucleophilic substitution; N(CF3)(2)] - anion; N; N-bis(trifluoromethyl)glycine; Fluorinated amino acids; Acidity; Ionic liquids in organic synthesis; PERFLUOROALKYL DERIVATIVES; NITROGEN; SPECTRA; AMIDES; ACID;

D O I：

10.1016/j.jfluchem.2017.11.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Convenient syntheses of organic compounds bearing the (CF3)(2)Ngroup by means of nucleophilic substitution reactions with the [N(CF3)(2)](-) anion were developed. The syntheses and properties of previously unknown N,N-bis(trifluoromethyl)glycine (CF3)(2)NCH2C(O)OH and its derivatives are described.

引用

页码：166 / 177

页数：12

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