Convenient synthesis of aliphatic (CF3)2N-compounds

被引：4
|
作者：
Breitenstein, Christoph [1 ]
Ignat'ev, Nikolai [2 ]
Frank, Walter [1 ]
机构：
[1] Heinrich Heine Univ, Inst Anorgan Chem & Strukturchem Mat & Strukturfo, Dusseldorf, Germany
[2] Merck KGaA, Darmstadt, Germany
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2018年 / 210卷
关键词：
Nucleophilic substitution; N(CF3)(2)] - anion; N; N-bis(trifluoromethyl)glycine; Fluorinated amino acids; Acidity; Ionic liquids in organic synthesis; PERFLUOROALKYL DERIVATIVES; NITROGEN; SPECTRA; AMIDES; ACID;
D O I：
10.1016/j.jfluchem.2017.11.007
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Convenient syntheses of organic compounds bearing the (CF3)(2)Ngroup by means of nucleophilic substitution reactions with the [N(CF3)(2)](-) anion were developed. The syntheses and properties of previously unknown N,N-bis(trifluoromethyl)glycine (CF3)(2)NCH2C(O)OH and its derivatives are described.
引用
收藏
页码：166 / 177
页数：12
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