Aerobic Oxidation of Hydroquinone Derivatives Catalyzed by Polymer-Incarcerated Platinum Catalyst

被引：91
|
作者：
Miyamura, Hiroyuki [1 ,2 ]
Shiramizu, Mika [1 ,2 ]
Matsubara, Ryosuke [1 ,2 ]
Kobayashi, Shu [1 ,2 ]
机构：
[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
[2] Univ Tokyo, Grad Sch Pharmaceut Sci, HFRE Div, ERATO Japan Sci Technol Agcy,Bunkyo Ku, Tokyo 1130033, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 42期
关键词：
hydroquinones; oxidation; platinum; polymers; supported catalysts;
D O I：
10.1002/anie.200802192
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) It's a lock-in! A remarkably wide substrate scope of hydroquinones are oxidized to quinones in high yields in a platinum-catalyzed process with as low as 0.05 mol% catalyst. The aerobic oxidation is catalyzed by platinum nanoclusters trapped in a styrene-based polymer network (see scheme, PI Pt=polymer-incarcerated nanoclusters). The catalyst could be reused at least 13 times without any loss of catalytic activity. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：8093 / 8095
页数：3
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