Photocatalytic Aerobic Oxidation of Alkenes into Epoxides or Chlorohydrins Promoted by a Polymer-Supported Decatungstate Catalyst

被引：16
|
作者：
Symeonidis, Theodoros S. [1 ]
Athanasoulis, Alexandros [1 ]
Ishii, Rikako [2 ]
Uozumi, Yasuhiro [2 ]
Yamada, Yoichi M. A. [2 ]
Lykakis, Ioannis N. [1 ]
机构：
[1] Aristotle Univ Thessaloniki, Dept Chem, Univ Campus, Thessaloniki 54124, Greece
[2] RIKEN Ctr Sustainable Resource Sci Hirosawa, Wako, Saitama 3510198, Japan
来源：
CHEMPHOTOCHEM | 2017年 / 1卷 / 10期
关键词：
aerobic oxidation; chlorohydrins; decatungstate; epoxides; polymer supports; METAL-ORGANIC FRAMEWORK; ASYMMETRIC EPOXIDATION; SINGLET OXYGEN; HYDROGEN-PEROXIDE; HETEROGENEOUS CATALYST; INORGANIC-COMPOUNDS; IONIC COPOLYMER; POLYOXOMETALATE; PHOSPHOTUNGSTATE; ALCOHOLS;
D O I：
10.1002/cptc.201700079
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An efficient photocatalytic method for the aerobic oxidation of alkenes to afford either the corresponding epoxides or chlorohydrins, depending on the solvent of choice, is presented. This effective approach uses a novel polymer-supported decatungstate catalyst bearing a poly(isopropylacrylamide alkylammonium) matrix and yields the corresponding products in moderate to excellent yields.
引用
收藏
页码：479 / 484
页数：6
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