Copper-catalyzed mild desulfonylation of vinyl sulfonyl molecules

被引：18
|
作者：
Jiang, Ying [1 ]
Fang, Wan-Yin [1 ]
Rakesh, K. P. [1 ]
Qin, Hua-Li [1 ]
机构：
[1] Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, Wuhan 430070, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2020年 / 7卷 / 13期
基金：
中国国家自然科学基金;
关键词：
HIGHLY ENANTIOSELECTIVE HYDROFORMYLATION; CROSS-COUPLING REACTIONS; OLEFIN-METATHESIS; TERMINAL ALKYNES; STEREOSELECTIVE CHLOROSULFONYLATION; TRANSFER HYDROGENATION; ARYL; FLUORIDES; WATER; ALLENES;
D O I：
10.1039/d0qo00468e
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first Cu-catalyzed chemical selective desulfonylation of vinyl sulfonyl fluorides and vinyl sulfonyl compounds to their corresponding olefins was developed using B(2)pin(2)-water as the reductant. This protocol featured a wide substrate scope, mild conditions and excellent functional group compatibility.
引用
收藏
页码：1696 / 1702
页数：7
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