Arabinose, Fucose, Ribodesose, Lyxose, and Ribose Used as Chiral Stationary Phases in HPLC

被引：4
|
作者：
Sun, W. Z. [1 ]
Yuan, L. M. [1 ]
机构：
[1] Yunnan Normal Univ, Dept Chem, Kunming 650092, Peoples R China
来源：
JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES | 2009年 / 32卷 / 04期
关键词：
Arabinose; Chiral stationary phase; Fucose; Lyxose; Ribodesose; Ribose; CHROMATOGRAPHIC-SEPARATION; CAPILLARY-ELECTROPHORESIS; SELECTORS; OLIGOSACCHARIDES; DERIVATIVES;
D O I：
10.1080/10826070802671549
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
In this paper, we present the first enantioseparations using arabinose, ribose, ribodesose, lyxose, and fucose as chiral selector bonded to silica gel via 3-(triethoxysilyl)propyl isocyanate in HPLC. These chiral stationary phases possess good enantioseparation selectivity in the normal-phase mode, and there is a big chiral discriminating complementary. This work indicates that monosaccharides could soon become very attractive as a new kind of chiral stationary phase for HPLC.
引用
收藏
页码：553 / 559
页数：7
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