Arabinose, Fucose, Ribodesose, Lyxose, and Ribose Used as Chiral Stationary Phases in HPLC

被引：4

作者：

Sun, W. Z. ^{[1
]}

Yuan, L. M. ^{[1
]}

机构：

[1] Yunnan Normal Univ, Dept Chem, Kunming 650092, Peoples R China

来源：

JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES | 2009年 / 32卷 / 04期

关键词：

Arabinose; Chiral stationary phase; Fucose; Lyxose; Ribodesose; Ribose; CHROMATOGRAPHIC-SEPARATION; CAPILLARY-ELECTROPHORESIS; SELECTORS; OLIGOSACCHARIDES; DERIVATIVES;

D O I：

10.1080/10826070802671549

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

In this paper, we present the first enantioseparations using arabinose, ribose, ribodesose, lyxose, and fucose as chiral selector bonded to silica gel via 3-(triethoxysilyl)propyl isocyanate in HPLC. These chiral stationary phases possess good enantioseparation selectivity in the normal-phase mode, and there is a big chiral discriminating complementary. This work indicates that monosaccharides could soon become very attractive as a new kind of chiral stationary phase for HPLC.

引用

页码：553 / 559

页数：7

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