Synthesis and Crystal Structure of the Triple-decker Complex [(η5-C5Me5)-Ru(μ,η5-1,3-C3B2Me5)RhCl-(Ph2PCH2)2]

被引：0

作者：

Nie, Yong ^{[1
,2
]}

Oeser, Thomas ^{[3
]}

Siebert, Walter ^{[1
]}

机构：

[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

[2] Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Peoples R China

[3] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2009年 / 64卷 / 01期

关键词：

Diborolyl; Ruthenium; Rhodium; Triple-decker Complexes; METAL-COMPLEXES; REACTIVITY; LIGAND;

D O I：

10.1515/znb-2009-0118

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimer [(eta(5)-C5Me5)Ru(C3B2Me5)RhCl](2) (2) reacts with 1,2-bis(diphenylphosphino)ethane (dppe) to give the triple-decker complex [(eta(5)-C5Me5)Ru(C3B2Me5)Rh-(dppe)Cl] (3). Its constitution follows from NMR and MS data, and a single-crystal X-ray diffraction study.

引用

页码：141 / 144

页数：4

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