Synthesis and Crystal Structure of the Triple-decker Complex [(η5-C5Me5)-Ru(μ,η5-1,3-C3B2Me5)RhCl-(Ph2PCH2)2]

被引：0
|
作者：
Nie, Yong [1 ,2 ]
Oeser, Thomas [3 ]
Siebert, Walter [1 ]
机构：
[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany
[2] Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Peoples R China
[3] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2009年 / 64卷 / 01期
关键词：
Diborolyl; Ruthenium; Rhodium; Triple-decker Complexes; METAL-COMPLEXES; REACTIVITY; LIGAND;
D O I：
10.1515/znb-2009-0118
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The dimer [(eta(5)-C5Me5)Ru(C3B2Me5)RhCl](2) (2) reacts with 1,2-bis(diphenylphosphino)ethane (dppe) to give the triple-decker complex [(eta(5)-C5Me5)Ru(C3B2Me5)Rh-(dppe)Cl] (3). Its constitution follows from NMR and MS data, and a single-crystal X-ray diffraction study.
引用
收藏
页码：141 / 144
页数：4
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