Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions

被引：31
|
作者：
Zhang, Yalei [1 ,3 ]
Shen, Zheng [1 ,2 ,3 ]
Zhou, Xuefei [1 ,3 ]
Zhang, Min [3 ]
Jin, Fangmin [1 ]
机构：
[1] Tongji Univ, Coll Environm Sci & Engn, Key Lab Yangtze River Water Environm MOE, State Key Lab Pollut Control & Resources Reuse, Shanghai 200092, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
[3] Tongji Univ, Inst Modern Agr Sci & Engn, Natl Engn Res Ctr Facil Agr, Shanghai 200092, Peoples R China
来源：
GREEN CHEMISTRY | 2012年 / 14卷 / 12期
基金：
中国国家自然科学基金;
关键词：
CONVERSION; BIODIESEL; OIL; OXIDATION; BIOMASS; TRANSESTERIFICATION; CATALYSTS; KINETICS; ETHANOL; FUELS;
D O I：
10.1039/c2gc36153a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
To discover the reaction mechanism for the production of hydrogen and lactic acid from glycerol under alkaline hydrothermal conditions, we identified the different intermediates involved during reactions by investigating the solvent isotope effect with H-1-NMR, H-2-NMR, LC-MS and Gas-MS analyses, and then proposed and proved a potential reaction mechanism.
引用
收藏
页码：3285 / 3288
页数：4
相关论文
共 50 条
  • [41] Vertical 3D Nanostructures Boost Efficient Hydrogen Production Coupled with Glycerol Oxidation Under Alkaline Conditions
    Shanlin Li
    Danmin Liu
    Guowei Wang
    Peijie Ma
    Xunlu Wang
    Jiacheng Wang
    Ruguang Ma
    Nano-Micro Letters, 2023, 15
  • [42] Solvent isotope effect on reduction of H2O or CO2 with glycerine under alkaline hydrothermal condition
    Shen, Zheng
    Gu, Minyan
    Zhou, Xuefei
    Zhang, Yalei
    Tongji Daxue Xuebao/Journal of Tongji University, 2015, 43 (05): : 722 - 728
  • [43] Hydrogen sulphide removal from the effluents of a phosphoric acid production unit by absorption into chlorinated seawater under alkaline conditions
    Boumnijel, Ibtissem
    Ben Amor, Hedi
    Chekir, Hassen
    Hajji, Nejib
    COMPTES RENDUS CHIMIE, 2016, 19 (04) : 517 - 524
  • [44] Effect of temperature on lactic acid production from cheese whey using Lactobacillus helveticus under batch conditions
    Tango, MSA
    Ghaly, AE
    BIOMASS & BIOENERGY, 1999, 16 (01): : 61 - 78
  • [45] Effect of temperature on lactic acid production from cheese whey using Lactobacillus helveticus under batch conditions
    Tango, M.S.A.
    Ghaly, A.E.
    Biomass and Bioenergy, 1999, 16 (01): : 61 - 78
  • [46] Chemicals from biomass: synthesis of lactic acid by alkaline hydrothermal conversion of sorbitol
    Ramirez-Lopez, Camilo A.
    Ochoa-Gomez, Jose R.
    Gil-Rio, Silvia
    Gomez-Jimenez-Aberasturi, Olga
    Torrecilla-Soria, Jesus
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2011, 86 (06) : 867 - 874
  • [47] The mechanism of cation and oxygen isotope exchange in alkali feldspars under hydrothermal conditions
    Niedermeier, Dominik R. D.
    Putnis, Andrew
    Geisler, Thorsten
    Golla-Schindler, Ute
    Putnis, Christine V.
    CONTRIBUTIONS TO MINERALOGY AND PETROLOGY, 2009, 157 (01) : 65 - 76
  • [48] The mechanism of cation and oxygen isotope exchange in alkali feldspars under hydrothermal conditions
    Dominik R. D. Niedermeier
    Andrew Putnis
    Thorsten Geisler
    Ute Golla-Schindler
    Christine V. Putnis
    Contributions to Mineralogy and Petrology, 2009, 157
  • [49] Production of Acrylic Acid from Biomass-Derived Fumaric Acid under Hydrothermal Conditions
    Yin, Guodong
    Zhong, Heng
    Yao, Guodong
    Jin, Fangming
    Zhao, Jianfu
    ENERGIES, 2021, 14 (17)
  • [50] Investigation on phase transformation mechanism of zeolite NaY under alkaline hydrothermal conditions
    Li, Peng
    Ding, Tian
    Liu, Liping
    Xiong, Guang
    MATERIALS CHARACTERIZATION, 2013, 86 : 221 - 231
12345