Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions

被引：31
|
作者：
Zhang, Yalei [1 ,3 ]
Shen, Zheng [1 ,2 ,3 ]
Zhou, Xuefei [1 ,3 ]
Zhang, Min [3 ]
Jin, Fangmin [1 ]
机构：
[1] Tongji Univ, Coll Environm Sci & Engn, Key Lab Yangtze River Water Environm MOE, State Key Lab Pollut Control & Resources Reuse, Shanghai 200092, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
[3] Tongji Univ, Inst Modern Agr Sci & Engn, Natl Engn Res Ctr Facil Agr, Shanghai 200092, Peoples R China
来源：
GREEN CHEMISTRY | 2012年 / 14卷 / 12期
基金：
中国国家自然科学基金;
关键词：
CONVERSION; BIODIESEL; OIL; OXIDATION; BIOMASS; TRANSESTERIFICATION; CATALYSTS; KINETICS; ETHANOL; FUELS;
D O I：
10.1039/c2gc36153a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
To discover the reaction mechanism for the production of hydrogen and lactic acid from glycerol under alkaline hydrothermal conditions, we identified the different intermediates involved during reactions by investigating the solvent isotope effect with H-1-NMR, H-2-NMR, LC-MS and Gas-MS analyses, and then proposed and proved a potential reaction mechanism.
引用
收藏
页码：3285 / 3288
页数：4
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