Construction of Two New Metal-Organic Entangled Frameworks Via Varying Flexible Bis(Imidazole)-based Auxiliary Ligands

被引：20
|
作者：
Lou, Xin-Hua [1 ]
Xu, Chen [1 ]
Li, Hong-Mei [1 ]
Zhang, Zhi-Jie [1 ]
Zhang, Hao [1 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
来源：
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2013年 / 23卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Hydrothermal synthesis; Entangled framework; Mixed ligands; Luminescence; COORDINATION POLYMERS; POLYCATENATION;
D O I：
10.1007/s10904-013-9829-6
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two new metal-organic entangled frameworks, namely [Cd(FA)(0.5)(bix)(1.5)(H2O)] (n) center dot nNO(3) (1) and [Cd(FA)(bib)(H2O)(2)] (n) (2) (FA = fumaric acid, bix = 4,4'-bis(imidazol-1-ylmethyl)benzene, bib = 1,4-bis(imidazolyl)butane), have been successfully hydrothermally synthesized through mixed ligands strategy. Single crystal X-ray diffraction analysis reveal that 1 is a 2D -> 3D polycatenated framework, while 2 is a triply interpenetrated 4-connected dia topological net. Moreover, both compounds exhibit intense luminescence emission at room temperature.
引用
收藏
页码：659 / 664
页数：6
相关论文
共 50 条
  • [11] Metal-organic frameworks built by flexible organic ligands
    [J]. Science Foundation in China, 2015, (02) : 5 - 5
  • [12] Assembly of new polyoxometalate-templated metal-organic frameworks based on flexible ligands
    Li, Na
    Mu, Bao
    Lv, Lei
    Huang, Rudan
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2015, 226 : 88 - 93
  • [13] Construction of two new Zn(II)-guanazole frameworks via varying organic carboxylate ligands
    Cui, Penglei
    Li, Xiaohui
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2015, 1081 : 182 - 186
  • [14] Two unprecedented 3D metal-organic polyrotaxane frameworks based on a new flexible tri(imidazole) ligand
    Wu, Hua
    Liu, Hai-Yan
    Liu, Bo
    Yang, Jin
    Liu, Ying-Ying
    Ma, Jian-Fang
    Liu, Yun-Yu
    Bai, Hong-Ye
    [J]. CRYSTENGCOMM, 2011, 13 (10): : 3402 - 3407
  • [15] Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands
    Liu, Min
    Yang, Zhipei
    Sun, Wenhao
    Li, Xiuping
    Li, Juan
    Ma, Jinshi
    Yang, Guoqiang
    [J]. INORGANICA CHIMICA ACTA, 2009, 362 (08) : 2884 - 2889
  • [16] Employing flexible ligands to construct metal-organic frameworks
    Soares, Arianna
    McManus, Greg
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [17] Controlling interpenetration in metal-organic frameworks by tuning the conformations of flexible bis(triazole) ligands
    He, Xiang
    Lu, Xiao-Peng
    Tian, Yu-Yang
    Li, Ming-Xing
    Zhu, Shourong
    Xing, Feifei
    Morris, Russell E.
    [J]. CRYSTENGCOMM, 2013, 15 (45) : 9437 - 9443
  • [18] Two Novel Cobalt(Ⅱ)/nickel(Ⅱ) Metal-organic Coordination Polymers Based on Flexible Polycarboxylic Acids and Rigid Bis(imidazole) Mix Ligands
    杨明星
    严智伟
    陈丽娟
    林星烨
    林深
    [J]. Chinese Journal of Structural Chemistry, 2020, 39 (01) : 147 - 153
  • [19] Construction of Two New Metal–Organic Frameworks from Pamoic Acid and N-Containing Auxiliary Ligands
    Chang-wei Lv
    Jing Li
    Zheng Hou
    Ming-kai Li
    [J]. Journal of Inorganic and Organometallic Polymers and Materials, 2014, 24 : 388 - 394
  • [20] Construction of Metal-Organic Frameworks Consisting of Dinuclear Metal Units Based on 5-Hydroxyisophthalate and Flexible Dipyridyl Ligands
    Li, Xiaoju
    Guan, Tena
    Guo, Xiaofang
    Li, Xinxiong
    Yu, Zhenjiang
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014 (13) : 2307 - 2316
12345