Construction of Two New Metal-Organic Entangled Frameworks Via Varying Flexible Bis(Imidazole)-based Auxiliary Ligands

被引：20
|
作者：
Lou, Xin-Hua [1 ]
Xu, Chen [1 ]
Li, Hong-Mei [1 ]
Zhang, Zhi-Jie [1 ]
Zhang, Hao [1 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
来源：
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2013年 / 23卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Hydrothermal synthesis; Entangled framework; Mixed ligands; Luminescence; COORDINATION POLYMERS; POLYCATENATION;
D O I：
10.1007/s10904-013-9829-6
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two new metal-organic entangled frameworks, namely [Cd(FA)(0.5)(bix)(1.5)(H2O)] (n) center dot nNO(3) (1) and [Cd(FA)(bib)(H2O)(2)] (n) (2) (FA = fumaric acid, bix = 4,4'-bis(imidazol-1-ylmethyl)benzene, bib = 1,4-bis(imidazolyl)butane), have been successfully hydrothermally synthesized through mixed ligands strategy. Single crystal X-ray diffraction analysis reveal that 1 is a 2D -> 3D polycatenated framework, while 2 is a triply interpenetrated 4-connected dia topological net. Moreover, both compounds exhibit intense luminescence emission at room temperature.
引用
收藏
页码：659 / 664
页数：6
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