Flexible Bis(imidazole).Based Ligands Oriented Co(II)-Glutarate Metal-Organic Frameworks: Syntheses, Structures and Properties

被引：1
|
作者：
Yang Yu-Ting [1 ]
Tu Chang-Zheng [1 ]
Wang Fan [1 ]
Zhang Yue [1 ]
Wang Jian-Ling [1 ]
Yin Hong-Ju [1 ]
Cheng Fei-Xiang [1 ]
机构：
[1] Qujing Normal Univ, Coll Chem & Environm Sci, Qujing 655011, Yunnan, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 37卷 / 04期
关键词：
crystal structure; glutaric acid; bis(imidazole) ligands; adsorption; magnetism; COORDINATION POLYMERS; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; COMPLEXES; SERIES;
D O I：
10.11862/CJIC.2021.086
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new Co(II)-MOFs based on flexible ligands, namely {[Co(glu)(bimb)]center dot 4H(2)O}(n) (1) and [Co(glu)(bix)(0.5)](n) (2) (H(2)glu=glutaric acid; bimb=1,4-bis(imidazol-1-yl) -butane; bix=1,4-bis(imidazol-1-yl-methylene)-benzene), have been hydrothermally synthesized and structurally characterized. Compound 1 displays non-interpenetrated (4,4) rhomboid grid layers. A 3D supramolecular framework is invoked through interlayer hydrogen bonding and pi...pi interactions. Upon dehydration the structure of 1 degraded irreversibly. Compound 2 exhibits a typical pillar-layered 3D framework with 4(12)6(3) topology, in which the Co(II) ion adopts a square pyramidal coordination geometry. Moreover, compound 1 exhibited significant adsorption activity towards methyl orange in aqueous solution, and 2 showed weak antiferromagnetic behavior.
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页码：735 / 743
页数：9
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