Tetracoordinate Imidazole-Based Boron Complexes for the Selective Detection of Picric Acid

被引：47
|
作者：
Dhanunjayarao, Kunchala [1 ]
Mukundam, Vanga [1 ]
Venkatasubbaiah, Krishnan [1 ]
机构：
[1] Natl Inst Sci Educ & Res, Sch Chem Sci, Bhubaneswar 752050, Orissa, India
来源：
INORGANIC CHEMISTRY | 2016年 / 55卷 / 21期
关键词：
METAL-ORGANIC FRAMEWORK; AGGREGATION-INDUCED EMISSION; PI-ELECTRON MATERIALS; NITROAROMATIC EXPLOSIVES; ORGANOBORON COMPOUNDS; EFFICIENT DETECTION; AQUEOUS-MEDIA; SOLID SUPPORT; POLYMERS; STATE;
D O I：
10.1021/acs.inorgchem.6b01767
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
N,N-Dimethylamine and N,N-diphenylaminedecorated highly fluorescent imidazole borates have been synthesized and investigated as new fluorophores for the selective detection of trinitrophenol/picric acid (PA). Structural studies of a probe 1 and PA (1.PPM) complex revealed that the adduct formed by the deprotonation of PA by the -NMe2 group along with weak interactions is responsible for the selective detection of PA over other polynitrated organic compounds.
引用
收藏
页码：11153 / 11159
页数：7
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