Synthesis of novel ruthenium complexes containing bidentate imidazole-based ligands

被引：42
|
作者：
Elgafi, S [1 ]
Field, LD [1 ]
Messerle, BA [1 ]
Hambley, TW [1 ]
Turner, P [1 ]
机构：
[1] UNIV SYDNEY,SCH CHEM,SYDNEY,NSW 2006,AUSTRALIA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 13期
关键词：
D O I：
10.1039/a700474e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ruthenium(II) complexes containing the bidentate imidazole-based ligands (MeN2H2C3)(2)CO L-1, (MeN2H2C3)(2)CHOH L-2 and (MeN2H2C3)(2)CH2 L-3 (where 1-MeN2H2C3 = 1-methylimidazol-2-yl), [Ru(PPh3)(2)H(CO)L-1]Cl 1, [Ru(PPh3)(2)H(CO)L-2]Cl 2 and [Ru(PPh3)(2)H(CO)L-3]Cl 3, were synthesized by the reaction of L-1-L-3 with [Ru(PPh3)(3)H(Cl)(CO)] in toluene. The complexes were characterised by NMR spectroscopy and the crystal structures of [Ru(PPh3)(2)H(CO)L-1]BF4 4 and [Ru(PPh3)(2)H(CO)L-2]OH 5 determined.
引用
收藏
页码：2341 / 2345
页数：5
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