Stable N-Phosphorylated Triazol-5-Ylidenes

被引：1

作者：

Kirilchuk, A. A. ^{[1
]}

Marchenko, A. P. ^{[1
]}

Koidan, H. G. ^{[1
]}

Zarudnitskii, E. V. ^{[1
]}

Huryeva, A. N. ^{[1
]}

Yurchenko, A. A. ^{[1
]}

Kostyuk, A. N. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02094 Kiev 94, Ukraine

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2013年 / 188卷 / 1-3期

关键词：

N-heterocyclic carbenes; carbene ligands; triazoles;

D O I：

10.1080/10426507.2012.741162

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel N-phosphorylated triazolium salts have been synthesized. They react with sodium bis(trimethylsilyl)amide to produce new stable N-phosphorylated triazole-5-ylidenes, which rearrange to C-phosphorylated triazoles under heating. The formation of two silver carbene complexes is described. Representative carbene and carbene complex structures were determined by X-ray study.

引用

页码：254 / 255

页数：2

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