Stable N-Phosphorylated Triazol-5-Ylidenes

被引：1
|
作者：
Kirilchuk, A. A. [1 ]
Marchenko, A. P. [1 ]
Koidan, H. G. [1 ]
Zarudnitskii, E. V. [1 ]
Huryeva, A. N. [1 ]
Yurchenko, A. A. [1 ]
Kostyuk, A. N. [1 ]
机构：
[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02094 Kiev 94, Ukraine
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2013年 / 188卷 / 1-3期
关键词：
N-heterocyclic carbenes; carbene ligands; triazoles;
D O I：
10.1080/10426507.2012.741162
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Novel N-phosphorylated triazolium salts have been synthesized. They react with sodium bis(trimethylsilyl)amide to produce new stable N-phosphorylated triazole-5-ylidenes, which rearrange to C-phosphorylated triazoles under heating. The formation of two silver carbene complexes is described. Representative carbene and carbene complex structures were determined by X-ray study.
引用
收藏
页码：254 / 255
页数：2
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