Synthesis of the first metallacarborane triple-decker complexes with a central cyclopentadienyl ligand

被引：18

作者：

Kudinov, AR ^{[1
]}

Petrovskii, PV ^{[1
]}

Meshcheryakov, VI ^{[1
]}

Rybinskaya, MI ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 07期

关键词：

metallacarboranes; triple-decker complexes; ruthenium; nickel;

D O I：

10.1007/BF02495304

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The previously unknown metallacarboranes (eta-C5R5)Ru(eta-9-Me2S-7,8-C2B9H10) (R = H or Me) and (eta-C5H5)Ni(eta-9-Me2S-7,8-C2B9H10) were prepared and used in the synthesis of the first metallacarborane triple-decker complexes with a central cyclopentadienyl ligand, viz., [(eta-C5R5)Ru(mu-eta:eta-C5Me5)Ru(eta-9-Me2S-7,8-C2B9H10)]PF6 (R = H or Me), [(eta-9-Me2S-7,8-C2B9H10)Ni(mu-eta:eta-C5H5)Ni(eta-9-Me2S-7,8-C2B9H10)]PF6, and [(eta-C5H5)Ni(mu-eta:eta-C5H5)Ni(eta-9-Me2S-7,8-C2B9H10)]BF4.

引用

页码：1356 / 1361

页数：6

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