Synthesis of the first metallacarborane triple-decker complexes with a central cyclopentadienyl ligand

被引：18
|
作者：
Kudinov, AR [1 ]
Petrovskii, PV [1 ]
Meshcheryakov, VI [1 ]
Rybinskaya, MI [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 07期
关键词：
metallacarboranes; triple-decker complexes; ruthenium; nickel;
D O I：
10.1007/BF02495304
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The previously unknown metallacarboranes (eta-C5R5)Ru(eta-9-Me2S-7,8-C2B9H10) (R = H or Me) and (eta-C5H5)Ni(eta-9-Me2S-7,8-C2B9H10) were prepared and used in the synthesis of the first metallacarborane triple-decker complexes with a central cyclopentadienyl ligand, viz., [(eta-C5R5)Ru(mu-eta:eta-C5Me5)Ru(eta-9-Me2S-7,8-C2B9H10)]PF6 (R = H or Me), [(eta-9-Me2S-7,8-C2B9H10)Ni(mu-eta:eta-C5H5)Ni(eta-9-Me2S-7,8-C2B9H10)]PF6, and [(eta-C5H5)Ni(mu-eta:eta-C5H5)Ni(eta-9-Me2S-7,8-C2B9H10)]BF4.
引用
收藏
页码：1356 / 1361
页数：6
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