In the present study various physical and chemical characteristics have been studied and may be used for quality control of main edible vegetable oils sold on the Algerian market, namely: Afia, elio, fleurial, La Belle and Oleor. Result obtained indicated that all oils were consistent with norms established indicative of edible oils with good quality: Free Fatty Acid ranged from 0.044 to 0.054%, peroxide value varied from 1.61 to 2, iodine value ranged from 124.07 to 129.91, saponification value (189.01 to 192.21), density at 20 degrees C (0.917-0.921) and refractive index at 40 degrees C (1.4663-1.4670). However, the oils recorded high PUFA content (mean 60%) suggesting that our oils highly unsaturated and may be susceptible to rancidity. "Fleurial" oil could be more sensitive to oxidation and thermal alteration when compared with the others; this oil had the lowest induction period (8.27 h), lowest activation energy (438.16KJ/mol) and the highest PUFA content (mean 65%); however, at the factory, this oil was enriched on vitamins A and D, which makes it suitable for use as a salad oil. (C) All Rights Reserved