Recent Developments for the Synthesis of Heterocycles Catalyzed by N-Heterocyclic Carbene

被引：10

作者：

Ding, Qiuping ^{[1
,2
]}

Fan, Xiaona ^{[3
]}

Wu, Jie ^{[4
]}

机构：

[1] Jiangxi Normal Univ, Minist Educ, Key Lab Funct Small Organ Mol, Nanchang 330022, Jiangxi, Peoples R China

[2] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China

[3] Gannan Med Univ, Sch Pharm, Ganzhou 341000, Jiangxi, Peoples R China

[4] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

CURRENT ORGANIC CHEMISTRY | 2014年 / 18卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Benzofuranone; chromone; heterocycles; lactam; lactone; N-heterocyclic carbene; organocatalyst; DIELS-ALDER REACTIONS; HIGHLY ENANTIOSELECTIVE SYNTHESIS; GAMMA-BUTYROLACTONES; 4+2 CYCLOADDITION; CONJUGATE UMPOLUNG; DIRECT ANNULATIONS; ALPHA; BETA-UNSATURATED ALDEHYDES; FUSED DIHYDROPYRANONES; COOPERATIVE CATALYSIS; HOMOENOLATE ADDITIONS;

D O I：

10.2174/1385272819666140201003238

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Heterocyclic carbenes (NHCs) as versatile nucleophilic organocatalysts have been extensively studied and also widely applied in organic reactions. The types of organic reactions catalyzed by N-heterocyclic carbenes are broad including benzoin condensation, Stetter reaction, a(3)-to-d(3) umpolung, ring-opening reaction, transesterification, and ring expansion polymerization. This review reports recent developments in the synthesis of heterocycles (such as lactams, lactones, chromones, and benzofuranones) catalyzed by N-heterocyclic carbenes.

引用

页码：700 / 718

页数：19

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