Recent Developments for the Synthesis of Heterocycles Catalyzed by N-Heterocyclic Carbene

被引：10
|
作者：
Ding, Qiuping [1 ,2 ]
Fan, Xiaona [3 ]
Wu, Jie [4 ]
机构：
[1] Jiangxi Normal Univ, Minist Educ, Key Lab Funct Small Organ Mol, Nanchang 330022, Jiangxi, Peoples R China
[2] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China
[3] Gannan Med Univ, Sch Pharm, Ganzhou 341000, Jiangxi, Peoples R China
[4] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
来源：
CURRENT ORGANIC CHEMISTRY | 2014年 / 18卷 / 06期
基金：
中国国家自然科学基金;
关键词：
Benzofuranone; chromone; heterocycles; lactam; lactone; N-heterocyclic carbene; organocatalyst; DIELS-ALDER REACTIONS; HIGHLY ENANTIOSELECTIVE SYNTHESIS; GAMMA-BUTYROLACTONES; 4+2 CYCLOADDITION; CONJUGATE UMPOLUNG; DIRECT ANNULATIONS; ALPHA; BETA-UNSATURATED ALDEHYDES; FUSED DIHYDROPYRANONES; COOPERATIVE CATALYSIS; HOMOENOLATE ADDITIONS;
D O I：
10.2174/1385272819666140201003238
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
N-Heterocyclic carbenes (NHCs) as versatile nucleophilic organocatalysts have been extensively studied and also widely applied in organic reactions. The types of organic reactions catalyzed by N-heterocyclic carbenes are broad including benzoin condensation, Stetter reaction, a(3)-to-d(3) umpolung, ring-opening reaction, transesterification, and ring expansion polymerization. This review reports recent developments in the synthesis of heterocycles (such as lactams, lactones, chromones, and benzofuranones) catalyzed by N-heterocyclic carbenes.
引用
收藏
页码：700 / 718
页数：19
相关论文
共 50 条
  • [21] Recent Developments in the Applications of Palladium Complexes Bearing N-Heterocyclic Carbene Ligands
    Mata, Jose A.
    Poyatos, Macarena
    CURRENT ORGANIC CHEMISTRY, 2011, 15 (18) : 3309 - 3324
  • [22] N-Heterocyclic Carbene Catalyzed Domino Reactions
    Grossmann, Andre
    Enders, Dieter
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (02) : 314 - 325
  • [23] N-Heterocyclic carbene-catalyzed oxidations
    Maki, Brooks E.
    Chan, Audrey
    Phillips, Eric M.
    Scheidt, Karl A.
    TETRAHEDRON, 2009, 65 (16) : 3102 - 3109
  • [24] N-Heterocyclic Carbene Catalyzed Hydrophosphonylation of Aldehydes
    Cai, Zhi-Hua
    Du, Guang-Fen
    He, Lin
    Gu, Cheng-Zhi
    Dai, Bin
    SYNTHESIS-STUTTGART, 2011, (13): : 2073 - 2078
  • [25] Computational predictions on the stereoselectivity of N-heterocyclic carbene catalyzed β-lactam synthesis
    Tang, Ke
    Wang, Jinhu
    Hou, Qianqian
    Cheng, Xueli
    Liu, Yongjun
    TETRAHEDRON-ASYMMETRY, 2011, 22 (09) : 942 - 947
  • [26] N-Heterocyclic carbene catalyzed synthesis of benzotrifluorides from enals and β-trifluoromethylenones
    Zhou, Bang-An
    Zhang, Chun-Lin
    Ye, Song
    ORGANIC CHEMISTRY FRONTIERS, 2023, 10 (19) : 4774 - 4778
  • [27] An Efficient N-Heterocyclic Carbene (NHC)-Catalyzed Synthesis of Polysubstituted Cyclopentene
    Li, Sha
    Yang, Wenhan
    Luo, Xian
    Yao, Changsheng
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2019, 39 (05) : 1404 - 1410
  • [28] Recent Advances on N-Heterocyclic Carbene-Palladium-catalyzed Heck Reaction
    Anju, Panthananickal Joseph
    Neetha, Mohan
    Anilkumar, Gopinathan
    CHEMISTRYSELECT, 2022, 7 (04):
  • [29] N-Heterocyclic Carbene Catalyzed Synthesis of Dihydroxybenzophenones from -Methylenals and Aurones
    Chen, Kun-Quan
    Luo, Zhi
    Gao, Zhong-Hua
    Ye, Song
    CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (13) : 3253 - 3256
  • [30] N-Heterocyclic Carbene Catalyzed Oxidative Macrolactonization: Total Synthesis of (+)-Dactylolide
    Lee, Kiyoun
    Kim, Hyoungsu
    Hong, Jiyong
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (23) : 5735 - 5738
12345