New chiral ferrocenyl building blocks for asymmetric reactions

被引：23
|
作者：
Schwink, L [1 ]
Knochel, P [1 ]
机构：
[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 21期
关键词：
D O I：
10.1016/S0040-4039(97)00722-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The new C-2-symmetrical ferrocenyl amines 2 and 3 are easily prepared starting from the ketones 4. Their utility is demonstrated for enantioselective deprotonation reactions and highly diastereoselective alkylations of the amides 7. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：3711 / 3714
页数：4
相关论文
共 50 条
  • [31] New chiral allylaminosilanes and their use in asymmetric Sakurai reactions
    Bonini, BF
    Comes-Franchini, M
    Fochi, M
    Mazzanti, G
    Ricci, A
    Varchi, G
    TETRAHEDRON-ASYMMETRY, 1998, 9 (17) : 2979 - 2981
  • [32] Synthesis and configurational assignment of chiral salicylic aldehydes: Novel building blocks for asymmetric catalysis
    Berkessel, A
    Vennemann, MR
    Lex, J
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2002, 2002 (16) : 2800 - 2807
  • [33] Asymmetric Heterogeneous Catalysis by Nanoporous Materials Using Privileged Ligands as Chiral Building Blocks
    Silva, Ana R.
    CURRENT ORGANIC CHEMISTRY, 2014, 18 (10) : 1226 - 1241
  • [34] Sequential asymmetric dihydroxylation and sulfoxidation of homoallylic sulfides. Stereochemical aspects of the preparation of new trifunctional chiral building blocks
    Skarzewski, J
    Wojaczynska, E
    Turowska-Tyrk, I
    TETRAHEDRON-ASYMMETRY, 2002, 13 (04) : 369 - 375
  • [35] Efficient approach to chiral ferrocenyl ligands via asymmetric hydrogenation of ferrocenyl ketone.
    Chan, ASC
    Lam, WS
    Kok, SHL
    Lam, FL
    Cheung, GHY
    Wu, J
    Au-Yeung, TTL
    Yeung, CH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U552 - U552
  • [36] Polyfunctional chiral building blocks 1
    Enders, D.
    Backhaus, D.
    Runsink, J.
    Angewandte Chemie (International Edition in English), 1994, 33 (20): : 2098 - 2100
  • [37] Synthesis of New Chiral Building Blocks for Novel Peptide Nucleic Acids
    吴杰
    许笑宇
    刘克良
    Chinese Journal of Chemistry, 2003, (05) : 566 - 573
  • [38] New uses of amino acids as chiral building blocks in organic synthesis
    Reetz, MT
    Lee, WK
    ORGANIC LETTERS, 2001, 3 (20) : 3119 - 3120
  • [39] FERROELECTRIC LIQUID-CRYSTALS WITH NEW CHIRAL BUILDING-BLOCKS
    KELLER, P
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1984, 102 (10): : 295 - 305
  • [40] Synthesis of new chiral building blocks for novel peptide nucleic acids
    Wu, J
    Xu, XY
    Liu, KL
    CHINESE JOURNAL OF CHEMISTRY, 2003, 21 (05) : 566 - 573
12345