New chiral ferrocenyl building blocks for asymmetric reactions

被引:23
|
作者
Schwink, L [1 ]
Knochel, P [1 ]
机构
[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY
关键词
D O I
10.1016/S0040-4039(97)00722-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The new C-2-symmetrical ferrocenyl amines 2 and 3 are easily prepared starting from the ketones 4. Their utility is demonstrated for enantioselective deprotonation reactions and highly diastereoselective alkylations of the amides 7. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:3711 / 3714
页数:4
相关论文
共 50 条
  • [21] CHIRAL BUILDING-BLOCKS - INSITU DERIVATIZATION IN THE CATALYTIC ASYMMETRIC EPOXIDATION
    HANSON, R
    KLUNDER, J
    KO, S
    MASAMUNE, H
    SHARPLESS, KB
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 192 : 174 - ORGN
  • [22] New chiral building blocks from tetrabromocyclopropene and furan
    Pelphrey, PM
    Abboud, EA
    Wright, DL
    JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (20): : 6931 - 6933
  • [23] Chiral carbohydrate building blocks with a new perspective: Revisited
    Witczak, ZJ
    CARBOHYDRATE SYNTHONS IN NATURAL PRODUCTS CHEMISTRY: SYNTHESIS, FUNCTIONALIZATION AND APPLICATIONS, 2003, 841 : 1 - 19
  • [24] Hydrotalcite catalysis for the synthesis of new chiral building blocks
    Rodilla, Jesus M.
    Neves, Patricia P.
    Pombal, Sofia
    Rives, Vicente
    Trujillano, Raquel
    Diez, David
    NATURAL PRODUCT RESEARCH, 2016, 30 (07) : 834 - 840
  • [26] A short synthesis of a chiral alcohol as a new chiral auxiliary for asymmetric reactions
    Kim, BM
    Park, JK
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1999, 20 (06) : 744 - 746
  • [27] Chiral ferrocenyl diphosphines for asymmetric transfer hydrogenation of acetophenone
    Cabou, J
    Brocard, J
    Pélinski, L
    TETRAHEDRON LETTERS, 2005, 46 (07) : 1185 - 1188
  • [28] New chiral phosphine ligands for catalytic asymmetric reactions
    Yamanoi, Y
    Imamoto, T
    REVIEWS ON HETEROATOM CHEMISTRY, 1999, 20 : 227 - 248
  • [29] Chiral hydroxy phosphines as ligands for asymmetric hydrogenation and versatile building blocks for hybrid ligands
    Börner, A
    CHIMICA OGGI-CHEMISTRY TODAY, 2000, 18 (06) : 48 - 52