Hydroxyester disaccharides from fruits of cape gooseberry (Physalis peruviana)

被引：25
|
作者：
Mayorga, H
Duque, C
Knapp, H
Winterhalter, P
机构：
[1] Univ Nacl Colombia, Dept Quim, Bogota, Colombia
[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Lebensmittelchem, D-38106 Braunschweig, Germany
来源：
PHYTOCHEMISTRY | 2002年 / 59卷 / 04期
关键词：
Physalic peruviana; Solanaceae; uchuva; cape gooseberry; aroma precusors; glycosides; hydroxyester glycosides;
D O I：
10.1016/S0031-9422(01)00467-8
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The 3-O-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranoside of ethyl 3-hydroxyoctanoate and the diastereomeric 3-O-alpha-L-arabinopyranosyl-(1-->6)-beta-D-glucopyranosides of (3R) and (3S)-butyl 3-hydroxybutanoate, respectively, were isolated by chromatographic methods from fruits of cape gooseberry (Physalis peruviana) harvested in Colombia. Their structures were identified by ESI-MS/ MS and NMR spectroscopy. The three glycoconjugates can be considered as immediate precursors of ethyl 3-hydroxyoctanoate and butyl 3-hydroxybutanoate, which are important aroma volatiles found in the fruit. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：439 / 445
页数：7
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